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In this study, the instability of black phosphorus is leveraged to induce the growth of the tungsten oxide film through its decomposition process, inspired by the 2D material\u2010assisted in situ growth (TAIG) method. This approach results in the preparation of large\u2010scale, high\u2010performance WO\n                    <jats:sub>3\u2010x<\/jats:sub>\n                    \u00b7nH\n                    <jats:sub>2<\/jats:sub>\n                    O (\n                    <jats:italic>n\u00a0<\/jats:italic>\n                    &lt;\u00a02) films. Characterization techniques and DFT calculations confirm efficient regulation of\u00a0structural water and oxygen vacancies during TAIG preparation. The WO\n                    <jats:sub>3\u2010x<\/jats:sub>\n                    \u00b7nH\n                    <jats:sub>2<\/jats:sub>\n                    O films exhibit excellent electrochromic (EC) properties, including high transmittance modulation (74.2%@1100\u00a0nm), fast switching time (\n                    <jats:italic>t<\/jats:italic>\n                    <jats:sub>c\u00a0<\/jats:sub>\n                    =\u00a05.5\u00a0s,\n                    <jats:italic>t<\/jats:italic>\n                    <jats:sub>b\u00a0<\/jats:sub>\n                    =\u00a03.8\u00a0s), high coloration efficiency (124.7\u00a0cm\n                    <jats:sup>2<\/jats:sup>\n                    \u00a0C\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), and superior cyclic stability (transmittance modulation retained 94.7% after 20\u00a0000 cycles). Ultra\u2010large\u00a0WO\n                    <jats:sub>3\u2010x<\/jats:sub>\n                    \u00b7nH\n                    <jats:sub>2<\/jats:sub>\n                    O film are prepared via a simple immersion process, and fabricated into a large\u2010area ESW under facile laboratory conditions, demonstrating the economic and practical feasibility of this approach in industrial\u2010scale production. Operated by the intelligent control circuit,\u00a0 the ESW\u00a0exhibits remarkable EC properties and cyclic stability This research represents a milestone in improving the performance and industrial\u2010scale production of ESWs, bridging the gap to the commercialization of EC technology.\n                  <\/jats:p>","DOI":"10.1002\/adma.202409790","type":"journal-article","created":{"date-parts":[[2024,10,22]],"date-time":"2024-10-22T08:55:09Z","timestamp":1729587309000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":49,"title":["Bridging to Commercialization: Record\u2010Breaking of Ultra\u2010Large and Superior Cyclic Stability Tungsten Oxide Electrochromic Smart Window"],"prefix":"10.1002","volume":"37","author":[{"given":"Maofei","family":"Tian","sequence":"first","affiliation":[{"name":"College of Materials and Metallurgy Guizhou University  Guiyang 550025 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0451-4474","authenticated-orcid":false,"given":"Rongzong","family":"Zheng","sequence":"additional","affiliation":[{"name":"College of Materials and Metallurgy Guizhou University  Guiyang 550025 China"},{"name":"State Key Laboratory of Electronic Thin Films and Integrated Devices National Engineering Research Center of Electromagnetic Radiation Control Materials School of Integrated Circuit Science and Engineering University of Electronic Science and Technology of China  Chengdu 610054 PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunyang","family":"Jia","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Electronic Thin Films and Integrated Devices National Engineering Research Center of Electromagnetic Radiation Control Materials School of Integrated Circuit Science and Engineering University of Electronic Science and Technology of China  Chengdu 610054 PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,10,22]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.rser.2022.113013"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2021.126854"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.xcrp.2023.101370"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202307223"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202308989"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2023.09.014"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.rser.2023.113355"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202403499"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202400760"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.148098"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2023.143644"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/admt.202000836"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2024.03.029"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.130306"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/smtd.202300850"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaelm.3c01079"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2017.12.030"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2022.10.047"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pmatsci.2017.04.003"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2NR04761F"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.optmat.2023.114421"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.130383"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.solidstatesciences.2022.106990"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.3390\/coatings13111879"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.3390\/nano10050821"},{"key":"e_1_2_7_26_1","volume":"15","author":"Dutta P.","year":"2023","journal-title":"ACS Appl. 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