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This study introduces a Ti\n                    <jats:sub>3<\/jats:sub>\n                    C\n                    <jats:sub>2<\/jats:sub>\n                    T\n                    <jats:sub>x<\/jats:sub>\n                    MXene@CuCo\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    (MCC) composite on a polyethylene (PE) separator to construct an ultrathin MXene@CuCo\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    \/PE (MCCP) film. The MCCP functional separator can deliver superior LiPSs adsorption\/catalysis capabilities via the MCC composite and regulate the Li\n                    <jats:sup>+<\/jats:sup>\n                    deposition through a conductive Ti\n                    <jats:sub>3<\/jats:sub>\n                    C\n                    <jats:sub>2<\/jats:sub>\n                    T\n                    <jats:sub>x<\/jats:sub>\n                    MXene framework, enhancing redox kinetics and cycling lifetime. When paired with sulfur\/carbon (S\/C) cathode and lithium metal anode, the resultant 10 Ah\u2010level pouch cell with the ultrathin MCCP separator achieves an energy density of 417\u00a0Wh kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    based on the whole cell and a stable running of 100 cycles under practical operation conditions (cathode loading = 10.0\u2009mg\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , negative\/positive areal capacity ratio (N\/P ratio) = 2, and electrolyte\/sulfur weight ratio (E\/S ratio) = 2.6\u2009\u00b5L mg\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). Furthermore, through a systematic evaluation of the as\u2010prepared Li\u2010S pouch cell, the study unveils the operational and failure mechanisms of LSBs under practical conditions. The achievement of ultrahigh energy density in such a large\u2010capacity lithium\u2010sulfur pouch cell will accelerate the commercialization of LSBs.\n                  <\/jats:p>","DOI":"10.1002\/adma.202410318","type":"journal-article","created":{"date-parts":[[2024,11,12]],"date-time":"2024-11-12T03:07:49Z","timestamp":1731380869000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":55,"title":["Multifunctional Ultrathin Ti\n                    <sub>3<\/sub>\n                    C\n                    <sub>2<\/sub>\n                    T\n                    <sub>x<\/sub>\n                    MXene@CuCo\n                    <sub>2<\/sub>\n                    O\n                    <sub>4<\/sub>\n                    \/PE Separator for Ultra\u2010High\u2010Energy\u2010Density and Large\u2010Capacity Lithium\u2010Sulfur Pouch Cells"],"prefix":"10.1002","volume":"37","author":[{"given":"Zimo","family":"Huang","sequence":"first","affiliation":[{"name":"Institute for Sustainable Transformation School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou 510006 China"},{"name":"Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center  Jieyang 515200 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuhao","family":"Liang","sequence":"additional","affiliation":[{"name":"Institute for Sustainable Transformation School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou 510006 China"},{"name":"Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center  Jieyang 515200 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenzhen","family":"Wu","sequence":"additional","affiliation":[{"name":"Centre for Catalysis and Clean Energy School of Environment and Science Gold Coast Campus Griffith University  Gold Coast QLD 4222 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Kong","sequence":"additional","affiliation":[{"name":"Science Center for Material Creation and Energy Conversion Institute of Frontier and Interdisciplinary Science Shandong University  Qingdao 266237 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maohui","family":"Bai","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Changsha University of Science and Technology  Changsha 410004 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng","family":"Li","sequence":"additional","affiliation":[{"name":"Institute for Sustainable Transformation School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou 510006 China"},{"name":"Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center  Jieyang 515200 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bo","family":"Hong","sequence":"additional","affiliation":[{"name":"School of Metallurgy and Environment Central South University  Changsha 410083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Taiyu","family":"Huang","sequence":"additional","affiliation":[{"name":"School of Metallurgy and Environment Central South University  Changsha 410083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Senchuan","family":"Huang","sequence":"additional","affiliation":[{"name":"Institute for Sustainable Transformation School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou 510006 China"},{"name":"Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center  Jieyang 515200 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