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However, most adopted mechanical ball milling and\/or high\u2010temperature annealing are ineffective approaches for large\u2010scale synthesis. Herein, a universal and scalable hydrate\u2010assisted strategy for the synthesis of oxychloride SSEs is developed based on the chemical reaction among alkali chlorides, AlCl<jats:sub>3<\/jats:sub>, and AlCl<jats:sub>3<\/jats:sub>\u00b76H<jats:sub>2<\/jats:sub>O. The synthesized aluminum\u2010based oxychloride SSEs possess a high Li<jats:sup>+<\/jats:sup> conductivity over 1\u00a0mS\u00a0cm<jats:sup>\u22121<\/jats:sup> at 30\u00a0\u00b0C. The final aluminum\u2010based oxychloride SSEs are structurally heterogeneous with nm\u2010sized LiCl\u2010like and LiAlCl<jats:sub>4<\/jats:sub> crystallites and large amounts of amorphous [Al<jats:italic><jats:sub>a<\/jats:sub><\/jats:italic>O<jats:italic><jats:sub>b<\/jats:sub><\/jats:italic>Cl<jats:italic><jats:sub>c<\/jats:sub><\/jats:italic>]<jats:sup>(2<\/jats:sup><jats:italic><jats:sup>b<\/jats:sup><\/jats:italic><jats:sup>+<\/jats:sup><jats:italic><jats:sup>c<\/jats:sup><\/jats:italic><jats:sup>\u22123<\/jats:sup><jats:italic><jats:sup>a<\/jats:sup><\/jats:italic><jats:sup>)\u2212<\/jats:sup> components. Faster local mobility of Li<jats:sup>+<\/jats:sup> ions in amorphous structures is verified and is attributable to weakened Li<jats:sup>+<\/jats:sup>\u2010X<jats:sup>\u2212<\/jats:sup> interactions ensured by the [Al<jats:italic><jats:sub>a<\/jats:sub><\/jats:italic>O<jats:italic><jats:sub>b<\/jats:sub><\/jats:italic>Cl<jats:italic><jats:sub>c<\/jats:sub><\/jats:italic>]<jats:sup>(2<\/jats:sup><jats:italic><jats:sup>b<\/jats:sup><\/jats:italic><jats:sup>+<\/jats:sup><jats:italic><jats:sup>c<\/jats:sup><\/jats:italic><jats:sup>\u22123<\/jats:sup><jats:italic><jats:sup>a<\/jats:sup><\/jats:italic><jats:sup>)\u2212<\/jats:sup> polyanions. The potential applications for this synthesis technique are further demonstrated by kilogram\u2010scale reactions and synthesis of other oxychloride SSEs including zirconium\u2010based and tantalum\u2010based analogs. These findings not only provide a new simple, scalable, and energy\u2010efficient synthesis route for oxychloride SSEs but also further promote their application in all\u2010solid\u2010state batteries.<\/jats:p>","DOI":"10.1002\/adma.202410402","type":"journal-article","created":{"date-parts":[[2024,11,12]],"date-time":"2024-11-12T03:13:39Z","timestamp":1731381219000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":60,"title":["Oxychloride Polyanion Clustered Solid\u2010State Electrolytes via Hydrate\u2010Assisted Synthesis for All\u2010Solid\u2010State Batteries"],"prefix":"10.1002","volume":"37","author":[{"given":"Guanzhi","family":"Wang","sequence":"first","affiliation":[{"name":"Eastern Institute for Advanced Study Eastern Institute of Technology  Ningbo Zhejiang 315200 P. R. China"},{"name":"Eastern Institute for Advanced Study Ningbo Key Laboratory of All\u2010Solid\u2010State Battery  Ningbo Zhejiang 315200 P. R. 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