{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T17:45:13Z","timestamp":1791395113500,"version":"4.3.3"},"reference-count":53,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2025,1,10]],"date-time":"2025-01-10T00:00:00Z","timestamp":1736467200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2025,2]]},"abstract":"Abstract<\/jats:title>\n \n Copper\u2010based electrocatalysts are recognized as crucial catalysts for CO\n 2<\/jats:sub>\n electroreduction into multi\u2010carbon products. However, achieving copper\u2010based electrocatalysts with adjustable valences via one\u2010step facile synthesis remains a challenge. In this study, Cu\/Cu\n 2<\/jats:sub>\n O heterostructure is constructed by adjusting the anion species of the Cu ions\u2010containing electrolyte during electrodeposition synthesis. Then, Cu\/Cu\n 2<\/jats:sub>\n O with tuned nanoarchitectures ranging from dendrites to polyhedrons is achieved by introducing transition metal ions as additives, leading to an adjustable interfacial microenvironment for CO\n 2<\/jats:sub>\n \/H\n 2<\/jats:sub>\n O adsorption on the Cu\/Cu\n 2<\/jats:sub>\n O electrodes. Additionally, the polyhedral Cu\/Cu\n 2<\/jats:sub>\n O catalysts are used as templates for depositing Ag single atoms (Ag\n SA<\/jats:sub>\n ), which are known as synergistic active sites for promoting\n *<\/jats:sup>\n CO to\n *<\/jats:sup>\n COH toward C\n 2+<\/jats:sub>\n products. The prepared Ag\n SA<\/jats:sub>\n \u2010Cu\/Cu\n 2<\/jats:sub>\n O catalyst is evaluated in a flow cell and exhibited a FE\n C2+<\/jats:sub>\n of 90.2% and a partial current density (jc\n 2+<\/jats:sub>\n ) of 426.6\u00a0mA\u00a0cm\n \u22122<\/jats:sup>\n for CO\n 2<\/jats:sub>\n electroreduction. As revealed by in situ Raman spectra and density functional theory calculations, the introduction of Ag single atoms slows down the reduction of Cu\n +<\/jats:sup>\n during CO\n 2<\/jats:sub>\n electroreduction, especially at a high current density. This work provides a promising paradigm for diverse control of the compositions and hydrophobicity of Cu\u2010based catalysts for selective CO\n 2<\/jats:sub>\n electroreduction to C\n 2+<\/jats:sub>\n products.\n <\/jats:p>","DOI":"10.1002\/adma.202411498","type":"journal-article","created":{"date-parts":[[2025,1,11]],"date-time":"2025-01-11T02:12:56Z","timestamp":1736561576000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":50,"title":["Additives\u2010Modified Electrodeposition for Synthesis of Hydrophobic Cu\/Cu\n 2<\/sub>\n O with Ag Single Atoms to Drive CO\n 2<\/sub>\n Electroreduction"],"prefix":"10.1002","volume":"37","author":[{"given":"Zining","family":"Zhang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Petroleum Molecular & Process Engineering Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular Engineering East China Normal University Shanghai 200062 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qi","family":"Fang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Petroleum Molecular & Process Engineering Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular Engineering East China Normal University Shanghai 200062 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xue","family":"Yang","sequence":"additional","affiliation":[{"name":"Sinopec Research Institute of Petroleum Processing Co. LTD Beijing 100083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shouwei","family":"Zuo","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Petroleum Molecular & Process Engineering Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular Engineering East China Normal University Shanghai 200062 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tao","family":"Cheng","sequence":"additional","affiliation":[{"name":"Sinopec Research Institute of Petroleum Processing Co. LTD Beijing 100083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7854-927X","authenticated-orcid":false,"given":"Yusuke","family":"Yamauchi","sequence":"additional","affiliation":[{"name":"Australian Institute for Bioengineering and Nanotechnology (AIBN) The University of Queensland Brisbane QLD 4072 Australia"},{"name":"Department of Materials Process Engineering Graduate School of Engineering Nagoya University Nagoya Aichi 464\u20108603 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7580-9459","authenticated-orcid":false,"given":"Jing","family":"Tang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Petroleum Molecular & Process Engineering Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular Engineering East China Normal University Shanghai 200062 China"},{"name":"Institute of Eco\u2010Chongming Shanghai 202162 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,1,10]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aav3506"},{"key":"e_1_2_7_1_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-020-2242-8"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-018-0084-7"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aay3111"},{"key":"e_1_2_7_2_3","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c01699"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00705"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202309319"},{"key":"e_1_2_7_3_3","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c10202"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202105118"},{"key":"e_1_2_7_4_2","first-page":"1","volume":"10","author":"Cai R.","year":"2023","journal-title":"Chem"},{"key":"e_1_2_7_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202205832"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c08005"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c03501"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-018-0092-x"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b01868"},{"key":"e_1_2_7_7_3","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms12123"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aas9100"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-019-0445-x"},{"key":"e_1_2_7_8_3","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c13529"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202302128"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-38524-3"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c02399"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c00467"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b02945"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c03717"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202214992"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202005798"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-017-0018-9"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4SC01735H"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c00206"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.2073115"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00535A"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-019-0269-8"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c01190"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.2c08480"},{"key":"e_1_2_7_23_1","volume":"34","author":"Ma Y.","year":"2022","journal-title":"Adv. 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