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In the 2D limit of an TaSe<jats:sub>2<\/jats:sub>\/SnSe bilayer with intact basal mirror symmetry (<jats:italic>M<\/jats:italic><jats:sub><jats:italic>z<\/jats:italic><\/jats:sub>), the mirror\u2010symmetric vdWH Ising superconductors show anomalous in\u2010plane magnetic field <jats:italic>B<\/jats:italic><jats:sub>\u2016<\/jats:sub>\u2010controlled enhancements in the critical temperature <jats:italic>T<\/jats:italic><jats:sub>c<\/jats:sub>, which is completely absent for multilayer vdWHs with broken <jats:italic>M<\/jats:italic><jats:sub><jats:italic>z<\/jats:italic><\/jats:sub> induced by orthorhombic stacking between nearest\u2010neighbour TaSe<jats:sub>2<\/jats:sub> monolayers. The experimental observations consistently reveal a mirror symmetry\u2010protected type\u2010III Ising state in the inversion asymmetric lattice of 1H\u2010TaSe<jats:sub>2<\/jats:sub>, which is predicted to be a mixture of spin\u2010singlet and spin\u2010triplet\u00a0states.<\/jats:p>","DOI":"10.1002\/adma.202411655","type":"journal-article","created":{"date-parts":[[2024,12,5]],"date-time":"2024-12-05T01:00:47Z","timestamp":1733360447000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Tunable Mirror\u2010Symmetric Type\u2010III Ising Superconductivity in Atomically\u2010Thin Natural Van der Waals Heterostructures"],"prefix":"10.1002","volume":"37","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3688-1618","authenticated-orcid":false,"given":"Xikang","family":"Sun","sequence":"first","affiliation":[{"name":"School of Physics, and State Key Laboratory of Silicon Materials and Advanced Semiconductor Materials 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