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However, the commercial initiator lead azide (LA) requires a high\u2010power density laser to detonate, with the minimum laser initiation energy (\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>min<\/jats:sub>\n                    ) of 2402 mJ. Currently, the laser\u2010ignitable metal complex\u2010based igniters still suffer from weak detonation capabilities and high\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>min<\/jats:sub>\n                    values. Here, the approach is first proposed to design laser ignition primary explosives within the high energy azide and tetrazole\u2010based energetic coordination compounds (ECCs), [Co(N\n                    <jats:sub>3<\/jats:sub>\n                    )(2\u2010bmttz)(H\n                    <jats:sub>2<\/jats:sub>\n                    O)]\n                    <jats:sub>2<\/jats:sub>\n                    <jats:bold>1<\/jats:bold>\n                    and [Co(N\n                    <jats:sub>3<\/jats:sub>\n                    )(2\u2010bmttz)(MeOH)]\n                    <jats:sub>2<\/jats:sub>\n                    <jats:bold>2<\/jats:bold>\n                    as additives to LA. Material\n                    <jats:bold>1e<\/jats:bold>\n                    with 4\u00a0wt.% of\n                    <jats:bold>1<\/jats:bold>\n                    in LA, exhibits ultra\u2010low laser initiation threshold (\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>min<\/jats:sub>\n                    = 1.6 mJ) and ultrafast corresponding time (\n                    <jats:italic>T<\/jats:italic>\n                    <jats:sub>min<\/jats:sub>\n                    = 0.2\u00a0ms). Specially, compared to LA, the threshold of\n                    <jats:bold>1e<\/jats:bold>\n                    is as low as 1\/1500 of that of LA. Moreover, 30\u00a0mg\n                    <jats:bold>1e<\/jats:bold>\n                    successfully detonates RDX with a laser energy of 1.6 mJ. Theoretical calculations and experiment results reveal that\n                    <jats:bold>1<\/jats:bold>\n                    exhibits the superior additive effect compared to\n                    <jats:bold>2<\/jats:bold>\n                    , attributed to its more enhanced ability to generate free radicals and higher photothermal conversion efficiency under laser conditions. This work represents a paradigm shift, with the potential to develop a laser\u2010driven micro\u2010detonator combining powerful detonation capabilities with exceptionally low laser initiation energy.\n                  <\/jats:p>","DOI":"10.1002\/adma.202414886","type":"journal-article","created":{"date-parts":[[2024,12,9]],"date-time":"2024-12-09T08:22:00Z","timestamp":1733732520000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":33,"title":["Structure\u2010Induced Energetic Coordination Compounds as Additives for Laser Initiation Primary Explosives"],"prefix":"10.1002","volume":"37","author":[{"given":"Meng","family":"Cui","sequence":"first","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 P. R. China"},{"name":"College of Chemistry and Materials Science Fujian Normal University  Fuzhou Fujian 350007 P. R. China"},{"name":"Fujian Science &amp; Technology Innovation Laboratory for Optoelectronic Information of China  Fuzhou Fujian 350108 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yun\u2010Fan","family":"Yan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rui\u2010Xuan","family":"Qian","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 P. R. China"},{"name":"College of Chemistry and Materials Science Fujian Normal University  Fuzhou Fujian 350007 P. R. China"},{"name":"Fujian Science &amp; Technology Innovation Laboratory for Optoelectronic Information of China  Fuzhou Fujian 350108 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bo\u2010Wen","family":"Fan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 P. R. China"},{"name":"College of Chemistry and Materials Science Fujian Normal University  Fuzhou Fujian 350007 P. R. China"},{"name":"Fujian Science &amp; Technology Innovation Laboratory for Optoelectronic Information of China  Fuzhou Fujian 350108 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hong\u2010Yi","family":"Bian","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 P. R. China"},{"name":"Fujian Science &amp; Technology Innovation Laboratory for Optoelectronic Information of China  Fuzhou Fujian 350108 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fei","family":"Wen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 P. R. China"},{"name":"University of Chinese Academy of Sciences  Beijing 100049 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian\u2010Gang","family":"Xu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 P. R. China"},{"name":"College of Material Engineering Fujian Agriculture and Forestry University  Fuzhou Fujian 350108 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7264-170X","authenticated-orcid":false,"given":"Fa\u2010Kun","family":"Zheng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 P. R. China"},{"name":"Fujian Science &amp; Technology Innovation Laboratory for Optoelectronic Information of China  Fuzhou Fujian 350108 P. R. China"},{"name":"University of Chinese Academy of Sciences  Beijing 100049 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7450-9702","authenticated-orcid":false,"given":"Guo\u2010Cong","family":"Guo","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 P. R. 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