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This review provides an overview of the concept and principles of SA cocatalyst in photocatalysis, emphasizing the intrinsic differences to SAs used in classic chemical catalysis. Key factors that influence the efficiency of SAs in photocatalytic reactions, particularly in photocatalytic hydrogen (H\n                    <jats:sub>2<\/jats:sub>\n                    ) production, are highlighted. This review further covers synthesis methods, stabilization strategies, and characterization techniques for common SAs used in photocatalysis. Notably, \u201creactive deposition\u201d method, which often shows a self\u2010homing effect and thus achieves a maximum utilization efficiency of SA cocatalysts, is emphasized. Furthermore, the applications of SA cocatalysts in various photocatalytic processes, including H\n                    <jats:sub>2<\/jats:sub>\n                    evolution, carbon dioxide reduction, nitrogen fixation, and organic synthesis, are comprehensively reviewed, along with insights into common artifacts in these applications. This review concludes by addressing the challenges faced by SACs in photocatalysis and offering perspectives on future developments, with the aim of informing and advancing research on SAs for photocatalytic energy conversion.\n                  <\/jats:p>","DOI":"10.1002\/adma.202414889","type":"journal-article","created":{"date-parts":[[2024,12,29]],"date-time":"2024-12-29T22:46:01Z","timestamp":1735512361000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":115,"title":["Single Atom Cocatalysts in Photocatalysis"],"prefix":"10.1002","volume":"37","author":[{"given":"Si\u2010Ming","family":"Wu","sequence":"first","affiliation":[{"name":"Department of Materials Science WW4\u2010LKO University of Erlangen\u2010Nuremberg  Martensstra\u00dfe 7 91058 Erlangen 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