{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T14:14:49Z","timestamp":1789740889296,"version":"4.0.1"},"reference-count":78,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2025,2,19]],"date-time":"2025-02-19T00:00:00Z","timestamp":1739923200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52122316"],"award-info":[{"award-number":["52122316"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52233005"],"award-info":[{"award-number":["52233005"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52073108"],"award-info":[{"award-number":["52073108"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2025,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Organic room temperature phosphorescence (ORTP) polymer materials have sparked considerable research interests in recent years, but their optical function is still limited for multi\u2010mode optical imaging. Herein, a feasible and universal approach is proposed to endow ORTP polymer materials with periodic refractive index modulation functions by holographic patterning. The key to this approach is to design a two\u2010stage stepwise crosslinking. Stage\u20101, with low crosslinking density (\u22640.75 mol\u00a0L<jats:sup>\u22121<\/jats:sup>), is phosphorescence\u2010silent but can provide greater free volume for monomer diffusion and thus facilitate the patterning of refractive index modulated holograms via photopolymerization\u2010induced phase separation. The dense crosslinking at stage\u20102 can turn on phosphorescence with the intensity rising by 144% when the crosslinking density increases from 3.77 to 4.12 mol\u00a0L<jats:sup>\u22121<\/jats:sup>. The enhanced phosphorescence is primarily ascribed to the increase of conformational distortion and spin\u2010orbit coupling of organic phosphors based on theoretical calculations. Eventually, the first example is demonstrated of holographic plastic with the unique capability of independently displaying holographic andphosphorescent images. This work not only provides a novel paradigm to impart added optical functions to ORTP polymer materials but also paves the way for the development of high\u2010security optical materials to combat counterfeiting.<\/jats:p>","DOI":"10.1002\/adma.202414894","type":"journal-article","created":{"date-parts":[[2025,2,20]],"date-time":"2025-02-20T01:01:10Z","timestamp":1740013270000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":33,"title":["High\u2010Security Plastic with Integrated Holographic and Phosphorescent Images"],"prefix":"10.1002","volume":"37","author":[{"given":"Ming","family":"Yao","sequence":"first","affiliation":[{"name":"Key Lab of Material Chemistry for Energy Conversion and Storage Ministry of Education School of Chemistry and Chemical Engineering Huazhong University of Science and Technology (HUST)  Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Wei","sequence":"additional","affiliation":[{"name":"Key Lab of Material Chemistry for Energy Conversion and Storage Ministry of Education School of Chemistry and Chemical Engineering Huazhong University of Science and Technology (HUST)  Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weiguo","family":"Qiao","sequence":"additional","affiliation":[{"name":"Key Lab of Material Chemistry for Energy Conversion and Storage Ministry of Education School of Chemistry and Chemical Engineering Huazhong University of Science and Technology (HUST)  Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yue","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Lab of Material Chemistry for Energy Conversion and Storage Ministry of Education School of Chemistry and Chemical Engineering Huazhong University of Science and Technology (HUST)  Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xingping","family":"Zhou","sequence":"additional","affiliation":[{"name":"Key Lab of Material Chemistry for Energy Conversion and Storage Ministry of Education School of Chemistry and Chemical Engineering Huazhong University of Science and Technology (HUST)  Wuhan 430074 China"},{"name":"State Key Laboratory of Materials Processing and Die &amp; Mould Technology HUST  Wuhan 430074 China"},{"name":"National Anti\u2010counterfeit Engineering Research Center HUST  Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhong'an","family":"Li","sequence":"additional","affiliation":[{"name":"Key Lab of Material Chemistry for Energy Conversion and Storage Ministry of Education School of Chemistry and Chemical Engineering Huazhong University of Science and Technology (HUST)  Wuhan 430074 China"},{"name":"State Key Laboratory of Materials Processing and Die &amp; Mould Technology HUST  Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0083-8589","authenticated-orcid":false,"given":"Haiyan","family":"Peng","sequence":"additional","affiliation":[{"name":"Key Lab of Material Chemistry for Energy Conversion and Storage Ministry of Education School of Chemistry and Chemical Engineering Huazhong University of Science and Technology (HUST)  Wuhan 430074 China"},{"name":"State Key Laboratory of Materials Processing and Die &amp; Mould Technology HUST  Wuhan 430074 China"},{"name":"National Anti\u2010counterfeit Engineering Research Center HUST  Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5097-7416","authenticated-orcid":false,"given":"Xiaolin","family":"Xie","sequence":"additional","affiliation":[{"name":"Key Lab of Material Chemistry for Energy Conversion and Storage Ministry of Education School of Chemistry and Chemical Engineering Huazhong University of Science and Technology (HUST)  Wuhan 430074 China"},{"name":"State Key Laboratory of Materials Processing and Die &amp; Mould Technology HUST  Wuhan 430074 China"},{"name":"National Anti\u2010counterfeit Engineering Research Center HUST  Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,2,19]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.ade5140"},{"key":"e_1_2_7_1_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.abi6860"},{"key":"e_1_2_7_1_3","doi-asserted-by":"publisher","DOI":"10.1126\/science.abj0039"},{"key":"e_1_2_7_1_4","doi-asserted-by":"publisher","DOI":"10.1038\/s41566-019-0560-x"},{"key":"e_1_2_7_1_5","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202213915"},{"key":"e_1_2_7_1_6","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202202150"},{"key":"e_1_2_7_1_7","doi-asserted-by":"publisher","DOI":"10.1039\/D3CS00753G"},{"key":"e_1_2_7_1_8","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202310130"},{"key":"e_1_2_7_1_9","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201808209"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-48473-0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202211117"},{"key":"e_1_2_7_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202401589"},{"key":"e_1_2_7_2_4","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-20908-y"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4259"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202206712"},{"key":"e_1_2_7_3_3","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-020-0223-z"},{"key":"e_1_2_7_3_4","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202208895"},{"key":"e_1_2_7_3_5","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202210489"},{"key":"e_1_2_7_3_6","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-021-01073-5"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c05213"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c10673"},{"key":"e_1_2_7_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202305126"},{"key":"e_1_2_7_4_4","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202104002"},{"key":"e_1_2_7_4_5","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202403773"},{"key":"e_1_2_7_4_6","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202306834"},{"key":"e_1_2_7_4_7","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-31554-3"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202301874"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c02076"},{"key":"e_1_2_7_5_3","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-40451-2"},{"key":"e_1_2_7_5_4","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202308848"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-43133-1"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c13264"},{"key":"e_1_2_7_6_3","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-40193-1"},{"key":"e_1_2_7_6_4","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-36105-y"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202301993"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202201558"},{"key":"e_1_2_7_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202217284"},{"key":"e_1_2_7_7_4","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202001192"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-022-01318-x"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10118-024-3110-z"},{"key":"e_1_2_7_8_3","doi-asserted-by":"publisher","DOI":"10.1021\/ja502366r"},{"key":"e_1_2_7_8_4","first-page":"722","volume":"53","author":"Guo H. X.","year":"2022","journal-title":"Acta Polym. Sin."},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202103192"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202315061"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c00698"},{"key":"e_1_2_7_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202105903"},{"key":"e_1_2_7_10_4","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201915053"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm5034436"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma500167x"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201803713"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.6b13129"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40843-019-9580-y"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-19422-4"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202202760"},{"key":"e_1_2_7_16_1","first-page":"34","volume":"2","author":"James D. T.","year":"2021","journal-title":"Light Adv. Manuf."},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202103192"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202105628"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202108333"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201203815"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/mz3001918"},{"key":"e_1_2_7_20_2","volume-title":"Principles of Polymer Chemistry","author":"Flory P. J.","year":"1953"},{"key":"e_1_2_7_20_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.compositesb.2015.09.017"},{"key":"e_1_2_7_20_4","doi-asserted-by":"publisher","DOI":"10.1016\/0032-3861(87)90165-0"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.3c02011"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-33273-1"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202005269"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.0c01903"},{"key":"e_1_2_7_23_3","doi-asserted-by":"publisher","DOI":"10.1021\/jp075248q"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100171a002"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201901672"},{"key":"e_1_2_7_24_3","doi-asserted-by":"publisher","DOI":"10.1038\/s41566-022-01106-8"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr60240a004"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b03867"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00060"},{"key":"e_1_2_7_26_3","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b11224"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/andp.19053220806"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.21939"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2QM00744D"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202414894","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T07:29:37Z","timestamp":1760340577000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202414894"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,2,19]]},"references-count":78,"journal-issue":{"issue":"12","published-print":{"date-parts":[[2025,3]]}},"alternative-id":["10.1002\/adma.202414894"],"URL":"https:\/\/doi.org\/10.1002\/adma.202414894","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,2,19]]},"assertion":[{"value":"2024-09-30","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-02-19","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2414894"}}