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Cu\u2010based catalysts are currently prioritized as the most effective means for this process, yet it remains a long\u2010term goal to achieve high product selectivity at elevated current densities. This study delved into exploring the influence of a topological poly(2\u2010aminoazulene) with a substantial dipole moment on modulating the Cu surface dipole field to augment the catalytic activity involved in CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction. The resulting Cu\/poly(2\u2010aminoazulene) heterojunction showcases a remarkable ethylene Faradaic efficiency of 68.9% even at a substantial current density of 1 A cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . Through in situ Raman and in situ Fourier\u2010transform infrared spectroscopy, poly(2\u2010aminoazulene)\u2010modified Cu electrode exhibits a heightened concentration of intermediates as compared to the bare Cu, proving advantageous for C\u2212C dimerization. Theoretical calculations demonstrate the reduced energy barrier for C\u2212C dimerization, and meanwhile impeding hydrogen evolution reaction on Cu\/poly(2\u2010aminoazulene) heterojunction, which are beneficial to CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction. The catalyst design in this study, incorporating dipole moment considerations, not only investigates the influence of dipole moment on electrochemical carbon dioxide reduction but also pioneers an innovative strategy to augment catalytic activity by elevating the micro\u2010concentration of reactants on catalyst surfaces.\n                  <\/jats:p>","DOI":"10.1002\/adma.202415092","type":"journal-article","created":{"date-parts":[[2024,12,30]],"date-time":"2024-12-30T08:28:39Z","timestamp":1735547319000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":40,"title":["Large Dipole Moment Enhanced CO\n                    <sub>2<\/sub>\n                    Adsorption on Copper Surface: Achieving 68.9% Catalytic Ethylene Faradaic Efficiency at 1.0 A cm\n                    <sup>\u22122<\/sup>"],"prefix":"10.1002","volume":"37","author":[{"given":"Chenbao","family":"Lu","sequence":"first","affiliation":[{"name":"The Soft2D Lab State Key Laboratory of Metal Matrix Composites Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing School of Chemistry and Chemical Engineering Shanghai Jiao Tong University  Shanghai 200240 China"},{"name":"Frontiers Science Center for Transformative Molecules Zhang Jiang Institute for Advanced Study Shanghai Jiao Tong University  Shanghai 201203 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qichuan","family":"He","sequence":"additional","affiliation":[{"name":"College of Chemistry Zhengzhou University  Zhengzhou Henan 450001 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Senhe","family":"Huang","sequence":"additional","affiliation":[{"name":"The Soft2D Lab State Key Laboratory of Metal Matrix Composites Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing School of Chemistry and Chemical Engineering Shanghai Jiao Tong University  Shanghai 200240 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