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Herein, the tandem upgrading of bio\u2010furans is reported to high\u2010yield BT<jats:italic>p<\/jats:italic>X by rationally constructing a versatile Pt<jats:sub>1<\/jats:sub>Sn<jats:sub>1<\/jats:sub> intermetallic coupling ordered\u2010mesoporous SnO<jats:sub>2<\/jats:sub> (OM\u2010SnO<jats:sub>2<\/jats:sub>) catalyst. It is shown that with increasing reduction temperature from 200 to 350<jats:sup>\u00a0<\/jats:sup>\u00b0C, Pt nanoparticles (NPs) are first formed on OM\u2010SnO<jats:sub>2<\/jats:sub>, then converted to Pt<jats:sub>3<\/jats:sub>Sn<jats:sub>1<\/jats:sub> intermetallic nanoparticles (iNPs), and finally to Pt<jats:sub>1<\/jats:sub>Sn<jats:sub>1<\/jats:sub> iNPs with a gradually\u2010thickened SnO<jats:sub>2<\/jats:sub> overlayer. Impressively, the Pt<jats:sub>1<\/jats:sub>Sn<jats:sub>1<\/jats:sub> iNPs and defect\u2010rich OM\u2010SnO<jats:sub>2<\/jats:sub> in the optimized Pt@OM\u2010SnO<jats:sub>2<\/jats:sub> can serve as the highly\u2010active species for the hydrogenolysis of 5\u2010hydroxymethylfuran to 2,5\u2010dimethylfuran and the aromatization of 2,5\u2010dimethylfuran with acrylic acid to <jats:italic>p<\/jats:italic>\u2010xylene, affording the highest yields of 99.1% and 96.1%, respectively. More importantly, it can perfectly realize the tandem upgrading of furan, furfural and 5\u2010hydroxymethylfuran to benzene, toluene and p\u2010xylene with high yields of 94.6%, 94.2% and 95.2%, respectively, representing a new tandem catalytic system to realize the high\u2010yield BT<jats:italic>p<\/jats:italic>X productions from their corresponding bio\u2010furans. This catalyst also shows good recyclability and excellent scalability, which together with its superior activity\/selectivity suggest a high potential for sustainable BT<jats:italic>p<\/jats:italic>X productions.<\/jats:p>","DOI":"10.1002\/adma.202415295","type":"journal-article","created":{"date-parts":[[2024,11,20]],"date-time":"2024-11-20T05:19:27Z","timestamp":1732079967000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Tandem Upgrading of Bio\u2010Furans to Benzene, Toluene, and <i>p<\/i>\u2010xylene by Pt<sub>1<\/sub>Sn<sub>1<\/sub> Intermetallic Coupling Ordered Mesoporous SnO<sub>2<\/sub> Catalyst"],"prefix":"10.1002","volume":"37","author":[{"given":"Shoukang","family":"Xiao","sequence":"first","affiliation":[{"name":"State Key Laboratory of Pulp and Paper Engineering School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510640 China"},{"name":"Guangdong Provincial Key Lab of Green Chemical Product Technology School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Pulp and Paper Engineering School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510640 China"},{"name":"Guangdong Provincial Key Lab of Green Chemical Product Technology School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liyu","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Pulp and Paper Engineering School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510640 China"},{"name":"Guangdong Provincial Key Lab of Green Chemical Product Technology School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yingwei","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Pulp and Paper Engineering School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510640 China"},{"name":"Guangdong Provincial Key Lab of Green Chemical Product Technology School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4132-4533","authenticated-orcid":false,"given":"Kui","family":"Shen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Pulp and Paper Engineering School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510640 China"},{"name":"Guangdong Provincial Key Lab of Green Chemical Product Technology School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,20]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.7b00105"},{"key":"e_1_2_8_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/aic.15144"},{"key":"e_1_2_8_1_3","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.6b00619"},{"key":"e_1_2_8_1_4","doi-asserted-by":"publisher","DOI":"10.1039\/C7GC00992E"},{"key":"e_1_2_8_1_5","doi-asserted-by":"publisher","DOI":"10.1038\/532435a"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2017.05.007"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201803828"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1134\/S0965544121010023"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs35188a"},{"key":"e_1_2_8_4_1","first-page":"1416","volume":"51","author":"Cheng Y.\u2010T.","year":"2011","journal-title":"Angew. 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