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However, in more practical environments, namely, the use of neutral media and air\u2010fed cathode environments, slow ORR kinetics and insufficient oxygen supply pose significant challenges to efficient H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    production at high current densities. In this work, mesoporous B\u2010doped carbons with novel curved B\n                    <jats:sub>4<\/jats:sub>\n                    C active sites, synthesized via a carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ) reduction using a pore\u2010former agent, to simultaneously achieve excellent 2e\n                    <jats:sup>\u2212<\/jats:sup>\n                    ORR activity and improved mass transfer properties are introduced. Through a combination of experimental analysis and theoretical calculations, it is confirmed that the curved B\n                    <jats:sub>4<\/jats:sub>\n                    C configuration, formed by mesopores in the carbon, demonstrates superior selectivity and activity for 2e\n                    <jats:sup>\u2212<\/jats:sup>\n                    ORR due to its weaker interaction with *OOH intermediates compared to planar B\n                    <jats:sub>4<\/jats:sub>\n                    C in neutral media. Moreover, the mesopores facilitate oxygen supply and suppress the hydrogen evolution reaction, achieving a Faradaic efficiency of 86.2% at 150\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    under air\u2010supplied conditions, along with an impressive O\n                    <jats:sub>2<\/jats:sub>\n                    utilization efficiency of 93.6%. This approach will provide a route to catalyst design for efficient H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    electrosynthesis in a practical environment.\n                  <\/jats:p>","DOI":"10.1002\/adma.202415712","type":"journal-article","created":{"date-parts":[[2025,1,15]],"date-time":"2025-01-15T05:04:48Z","timestamp":1736917488000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":50,"title":["Mesoporous Boron\u2010Doped Carbon with Curved B\n                    <sub>4<\/sub>\n                    C Active Sites for Highly Efficient H\n                    <sub>2<\/sub>\n                    O\n                    <sub>2<\/sub>\n                    Electrosynthesis in Neutral Media and Air\u2010Supplied Environments"],"prefix":"10.1002","volume":"37","author":[{"given":"Jae Won","family":"Choi","sequence":"first","affiliation":[{"name":"Extreme Materials Research Center Korea Institute of Science and Technology  14\u2010gil 5 Hwarang\u2010ro, Seongbuk\u2010gu Seoul 02792 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ayeong","family":"Byeon","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering Chungbuk National University  Cheongju Chungbuk 28644 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sooyeon","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Chemistry Myongji University  Yongin 17058 Republic of Korea"},{"name":"Computational Science Research Center Korea Institute of Science and Technology  14\u2010gil 5 Hwarang\u2010ro, Seongbuk\u2010gu Seoul 02792 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chang\u2010Kyu","family":"Hwang","sequence":"additional","affiliation":[{"name":"Extreme 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Chan","family":"Yun","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology  291 Daehak\u2010ro, Yuseong\u2010gu Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sae Yane","family":"Paek","sequence":"additional","affiliation":[{"name":"Extreme Materials Research Center Korea Institute of Science and Technology  14\u2010gil 5 Hwarang\u2010ro, Seongbuk\u2010gu Seoul 02792 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jin Hyeung","family":"Kim","sequence":"additional","affiliation":[{"name":"Extreme Materials Research Center Korea Institute of Science and Technology  14\u2010gil 5 Hwarang\u2010ro, Seongbuk\u2010gu Seoul 02792 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Giho","family":"Jeong","sequence":"additional","affiliation":[{"name":"Extreme Materials Research Center Korea Institute of Science and Technology  14\u2010gil 5 Hwarang\u2010ro, Seongbuk\u2010gu Seoul 02792 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Seung Yong","family":"Lee","sequence":"additional","affiliation":[{"name":"Extreme Materials Research Center Korea Institute of Science and Technology  14\u2010gil 5 Hwarang\u2010ro, Seongbuk\u2010gu Seoul 02792 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Joonhee","family":"Moon","sequence":"additional","affiliation":[{"name":"Research Center for Materials Analysis Korea Basic Science Institute  169\u2010148, Gwahak\u2010ro, Yuseong\u2010gu Daejeon 34133 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sang Soo","family":"Han","sequence":"additional","affiliation":[{"name":"Computational Science Research Center Korea Institute of Science and Technology  14\u2010gil 5 Hwarang\u2010ro, Seongbuk\u2010gu Seoul 02792 Republic of 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