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However, the synthesis of isoindolinone derivatives typically requires multi\u2010step procedures or the use of palladium\u2010based catalysts, which are often hampered by low reaction yields and high costs. Recently, covalent organic frameworks (COFs)\u2014emerging crystalline and porous materials\u2014have gained considerable attention for their applications in various organic transformations, particularly in C\u2500H functionalization, cross\u2010coupling and redox reactions. Although COFs have been extensively studied for photocatalysis, the development of sustainable heterogeneous catalysts using low\u2010cost transition metal\u2010based photosensitizers is still in its early stages. Herein, a strategy is presented to incorporate a copper\u2010Xantphos complex with a tetrahedral Cu(I) geometry into a crystalline and porous COF matrix. This modification enables unprecedented simultaneous electron and energy transfer efficiency during photocatalysis. The Cu\u2013Xantphos coordinated COF exhibits potent photocatalytic activity for the synthesis of isoindolinone derivatives via C\u2500Br and C\u2500H bond cleavage followed by C\u2500C bond formation. In addition, the catalyst shows excellent recyclability as it can be rejuvenated by reintroducing the Cu\u2013Xantphos complex after multiple photocatalytic cycles\u2014highlighting its potential as a sustainable and cost\u2010effective solution for valuable organic transformations.<\/jats:p>","DOI":"10.1002\/adma.202416100","type":"journal-article","created":{"date-parts":[[2025,3,12]],"date-time":"2025-03-12T01:41:16Z","timestamp":1741743676000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Xantphos\u2013Cu\u2010Decorated Covalent Organic Frameworks for C\u2500H Arylation through Sensitized Electron Transfer"],"prefix":"10.1002","volume":"37","author":[{"given":"Akhtar","family":"Alam","sequence":"first","affiliation":[{"name":"Department of Chemical and Biological Sciences S. N. 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