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The stimuli\u2010responsive behavior of common multiple stimuli\u2010responsive materials are independent of each other, causing the lack of multiplicity and identification for information technology, which is easy to decode. Herein, QIPA\u2010Eu\u20101 and QIPA\u2010Eu\u20102 isomers were prepared from QIPA and EuCl\n                    <jats:sub>3<\/jats:sub>\n                    \u00b76H\n                    <jats:sub>2<\/jats:sub>\n                    O in different solvent thermal conditions for building sequential stimuli\u2010response (SSR) system. Solvent\u2010driven structural transformations of the isomers into QIPA\u2010Eu\u20103 occurred, along with color change and fluorescence emission variation ascribed to the generation of QIPA aggregates. Furthermore, QIPA\u2010Eu\u20103 displayed excellent photochromic behaviors. Combining theoretical calculation with well\u2010defined experiments to reveal the mechanism, it was found that light drove the change in the dihedral angles between the quinoline nucleus and adjacent benzene rings in QIPA aggregates. Finally, on the basis of sequential stimuli\u2010induced stepwise responsive behavior of QIPA\u2010Eu\u20101, the sequential logic gate and time\u2010dependent fluorescence dynamic anti\u2010counterfeiting pattern were successfully constructed. This study provided a new perspective for design and construction of SSR system, which showed promising potential in the fields of data transmission and information encryption.\n                  <\/jats:p>","DOI":"10.1002\/adma.202417822","type":"journal-article","created":{"date-parts":[[2025,2,5]],"date-time":"2025-02-05T04:12:58Z","timestamp":1738728778000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Sequential Stimuli\u2010Response System of Eu\u2010MOF Isomers"],"prefix":"10.1002","volume":"37","author":[{"given":"Wenwen","family":"Fan","sequence":"first","affiliation":[{"name":"School of Chemical Science and Technology Key Laboratory of Medicinal Chemistry for Natural Resource Yunnan University  No. 2 North Cuihu Road Kunming 650091 P. R. 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