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Herein, based on two kinds of biomolecule\u2010MOFs (Bio\u2010MOFs) with favorable biocompatibility and degradation\u2010reconstruction characteristics, we have established a self\u2010powered muti\u2010functional device to achieve an efficient and broad\u2010spectrum environmental energy collection and biomedical applications. Combining Zn(II) and carnosine\u2010based Zn\u2010Car_MOF possessing a high piezoelectric response (\n                    <jats:italic>d<\/jats:italic>\n                    <jats:sub>33<\/jats:sub>\n                    = 11.17 pm V\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) with patterned polydimethylsiloxane (PDMS) film, a tribo\u2010piezoelectric hybrid nanogenerator (TPHG) is constructed with a synergy output of triboelectric and piezoelectric effects. The Zn\u2010Car_TPHG demonstrates a high output performance (131\u00a0V at 100\u00a0kPa) and a wide range of pressure response (1\u00a0Pa\u2013100\u00a0kPa), possessing applications in environmental energy collection and biomedical sensors. To expand the application of the wearable device, a conductive hexagonal prism MOF (Cu\n                    <jats:sub>3<\/jats:sub>\n                    (2,3,6,7,10,11\u2010hexahydroxytriphenylene)\n                    <jats:sub>2<\/jats:sub>\n                    (Cu\u2010HHTP)) is synthesized and employed to load thymol (Thy). Cooperating with Zn\u2010Car_TPHG, the resulting Cu\u2010HHTP\/Thy can achieve an efficient self\u2010powered ROS (singlet oxygen (\n                    <jats:sup>1<\/jats:sup>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    ) and hydroxyl radical (\u00b7OH)) generation and drug synergistic broad\u2010spectrum sterilization effect (efficiency \u2265 98%). In a word, the flexible wearable device based on the muti\u2010functional Bio\u2010MOFs is sustainable and environmentally friendly, possessing wide application potential in fields of environmental energy collection, biosensors, and self\u2010powered antibacterial.\n                  <\/jats:p>","DOI":"10.1002\/adma.202418207","type":"journal-article","created":{"date-parts":[[2025,1,22]],"date-time":"2025-01-22T02:10:42Z","timestamp":1737511842000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":56,"title":["A Tribo\/Piezoelectric Nanogenerator Based on Bio\u2010MOFs for Energy Harvesting and Antibacterial Wearable Device"],"prefix":"10.1002","volume":"37","author":[{"given":"Yuqi","family":"Wang","sequence":"first","affiliation":[{"name":"College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"},{"name":"Key Laboratory of Smart Biomaterials of Zhejiang Province and Center for Bionanoengineering Key Laboratory of Biomass Chemical Engineering of the Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peipei","family":"Su","sequence":"additional","affiliation":[{"name":"College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhang","family":"Lin","sequence":"additional","affiliation":[{"name":"College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaolin","family":"Li","sequence":"additional","affiliation":[{"name":"ZJU\u2010Hangzhou Global Scientific and Technological Innovation Center Zhejiang University  Hangzhou 310027 China"},{"name":"Engineering Research Center of Functional Materials Intelligent Manufacturing of Zhejiang Province ZJU\u2010Hangzhou Global Scientific and Technological Innovation Center  Hangzhou 311215 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kangbo","family":"Chen","sequence":"additional","affiliation":[{"name":"College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tingting","family":"Ye","sequence":"additional","affiliation":[{"name":"College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"},{"name":"Key Laboratory of Smart Biomaterials of Zhejiang Province and Center for Bionanoengineering Key Laboratory of Biomass Chemical Engineering of the Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yaping","family":"Li","sequence":"additional","affiliation":[{"name":"College of Chemical and Biological Engineering 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