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In particular, the alloying of the recovered M components with Pt and applied as cathode catalysts have not yet been reported. Herein, a fresh L1\n                    <jats:sub>2<\/jats:sub>\n                    \u2010type Pt\n                    <jats:sub>3<\/jats:sub>\n                    \u00a0M medium\u2010entropy intermetallic nanoparticle is first proposed, confined on N\u2010doped carbon matrix (L1\n                    <jats:sub>2<\/jats:sub>\n                    \u2010Pt\n                    <jats:sub>3<\/jats:sub>\n                    (Ni\n                    <jats:sub>1\/3<\/jats:sub>\n                    Co\n                    <jats:sub>1\/3<\/jats:sub>\n                    Mn\n                    <jats:sub>1\/3<\/jats:sub>\n                    )@N\u2010C) based on spent 111 typed LiNi\n                    <jats:sub>1\u2010x\u2010y<\/jats:sub>\n                    Mn\n                    <jats:sub>x<\/jats:sub>\n                    Co\n                    <jats:sub>y<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    cathode. This well\u2010defined catalyst combines both features of long\u2010range order L1\n                    <jats:sub>2<\/jats:sub>\n                    face\u2010centered cubic structure and short\u2010range disorder in M sites. The former contributes to enhancing the structural stability, and the latter further facilitates deeply activating the catalytic activity of Pt sites. Experiments and theoretical results demonstrate that the local coordination environment and electronic distribution of Pt are both fundamentally modulated via surrounding disordered Ni, Co, and Mn atoms, which greatly optimize the affinity toward oxygen\u2010containing intermediates and facilitate the deposition\/decomposition kinetics of the thin\u2010film Li\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    discharge products. Specifically, the L1\n                    <jats:sub>2<\/jats:sub>\n                    \u2010Pt\n                    <jats:sub>3<\/jats:sub>\n                    (Ni\n                    <jats:sub>1\/3<\/jats:sub>\n                    Co\n                    <jats:sub>1\/3<\/jats:sub>\n                    Mn\n                    <jats:sub>1\/3)<\/jats:sub>\n                    @N\u2010C catalyst exhibits an ultra\u2010low overpotential of 0.48\u00a0V and achieves 220 cycles at 400\u00a0mA g\n                    <jats:sup>\u22121<\/jats:sup>\n                    under 1000 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . The work provides important insights for the recycling of spent lithium\u2010ion batteries into advanced catalyst\u2010related applications.\n                  <\/jats:p>","DOI":"10.1002\/adma.202418963","type":"journal-article","created":{"date-parts":[[2025,4,25]],"date-time":"2025-04-25T08:10:54Z","timestamp":1745568654000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":23,"title":["Upcycling Spent Lithium\u2010Ion Batteries: Constructing Bifunctional Catalysts Featuring Long\u2010Range Order and Short\u2010Range Disorder for Lithium\u2010Oxygen Batteries"],"prefix":"10.1002","volume":"37","author":[{"given":"Yu","family":"Tian","sequence":"first","affiliation":[{"name":"College of Electromechanical Engineering Shandong Engineering Laboratory for Preparation and Application of High\u2010Performance Carbon\u2010Materials Qingdao University of Science &amp; Technology  Qingdao 266061 P. R. 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