{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,14]],"date-time":"2026-09-14T23:20:39Z","timestamp":1789428039869,"version":"build-2803163510"},"reference-count":32,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2025,3,4]],"date-time":"2025-03-04T00:00:00Z","timestamp":1741046400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,3,4]],"date-time":"2025-03-04T00:00:00Z","timestamp":1741046400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100010040","name":"Taishan Scholar Project of Shandong Province","doi-asserted-by":"publisher","award":["tsqn201909062"],"award-info":[{"award-number":["tsqn201909062"]}],"id":[{"id":"10.13039\/501100010040","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007129","name":"Natural Science Foundation of Shandong Province","doi-asserted-by":"publisher","award":["ZR2021ZD24"],"award-info":[{"award-number":["ZR2021ZD24"]}],"id":[{"id":"10.13039\/501100007129","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2025,4]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Lithium\u2010chlorine (Li\u2010Cl\n                    <jats:sub>2<\/jats:sub>\n                    ) secondary batteries are emerging as promising candidates for high\u2010energy\u2010density power sources and an extensive operational temperature range. However, conventional electrode materials suffer from weak adsorption for\u00a0chlorine gas (Cl\n                    <jats:sub>2<\/jats:sub>\n                    ) and low conversion efficiency of lithium chloride (LiCl), leading to significant loss of chlorine\u2010based active materials. This issue hampers the cyclability of Li\u2010Cl\n                    <jats:sub>2<\/jats:sub>\n                    batteries. In this work, it is demonstrated that synergistic Cl\n                    <jats:sub>2<\/jats:sub>\n                    adsorption on the electrode surface and the energy barrier for LiCl reactions are crucial for enhancing Cl\n                    <jats:sub>2<\/jats:sub>\n                    \/LiCl conversion efficiency. Consequently, a cobalt (Co) single\u2010atom site catalyst with a Co\u2010N\n                    <jats:sub>4<\/jats:sub>\n                    coordination environment has been developed, which significantly diminishes the transformation barrier of solid LiCl particles into Cl\n                    <jats:sub>2<\/jats:sub>\n                    and concurrently enhances the chemical adsorption of Cl\n                    <jats:sub>2<\/jats:sub>\n                    , facilitating uniform nucleation of LiCl. As a result, the Li\u2010Cl\n                    <jats:sub>2<\/jats:sub>\n                    @Co\u2010NC battery developed has achieved a 0.6\u00a0V reduction in polarization voltage under high current densities, effectively addressing the issue of low conversion efficiency between Cl\n                    <jats:sub>2<\/jats:sub>\n                    and LiCl. At room temperature, the Li\u2010Cl\n                    <jats:sub>2<\/jats:sub>\n                    @Co\u2010NC battery achieves over 600 cycles at 1500\u00a0mA\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ; At \u221240\u00a0\u00b0C, it reaches 650 cycles at 500\u00a0mA\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . The research overcomes the cycle stability barrier in high\u2010current Li\u2010Cl\n                    <jats:sub>2<\/jats:sub>\n                    batteries and offers a strategy for batteries with a wide temperature range and long cycle life.\n                  <\/jats:p>","DOI":"10.1002\/adma.202418990","type":"journal-article","created":{"date-parts":[[2025,3,11]],"date-time":"2025-03-11T16:55:31Z","timestamp":1741712131000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":27,"title":["Co Single\u2010Atom Catalysis for High\u2010Efficiency LiCl\/Cl\n                    <sub>2<\/sub>\n                    Conversion in Rechargeable Lithium\u2010Chlorine Batteries"],"prefix":"10.1002","volume":"37","author":[{"given":"Peicai","family":"Li","sequence":"first","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing College of Chemical Engineering China University of Petroleum (East China)  Qingdao 266580 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenyu","family":"Ma","sequence":"additional","affiliation":[{"name":"College of New Energy China University of Petroleum (East China)  Qingdao 266580 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yufeng","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing College of Chemical Engineering China University of Petroleum (East China)  Qingdao 266580 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shibo","family":"Zhai","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering China University of Petroleum (East China)  Qingdao 266580 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guanzhong","family":"Ma","sequence":"additional","affiliation":[{"name":"College of New Energy China University of Petroleum (East China)  Qingdao 266580 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Debing","family":"Kong","sequence":"additional","affiliation":[{"name":"College of New Energy China University of Petroleum (East China)  Qingdao 266580 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0157-6098","authenticated-orcid":false,"given":"Zhongtao","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing College of Chemical Engineering China University of Petroleum (East China)  Qingdao 266580 P. R. 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