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However, the aggregation of catalyst nanoparticles diminishes the active surface area. Moreover, densely packed catalyst\u2010modified layers often hinder ion transport rates and impede access to the catalytic sites. To overcome these challenges, a strategy is reported for modifying commercial separators, using wood nanocellulose as a building block to construct hierarchical P\u2010doped MoO\n                    <jats:sub>2\u2212x<\/jats:sub>\n                    nanoparticles anchored on N, P co\u2010doped porous carbon (P\u2010MoO\n                    <jats:sub>2\u2212x<\/jats:sub>\n                    \/NPC). The web\u2010like entangled nanocellulose forms a framework for the in situ polymerization of polyaniline, providing abundant anchoring sites for MoO\n                    <jats:sub>2<\/jats:sub>\n                    nanoparticles. The addition of P atoms optimizes the d\u2010band center of MoO\n                    <jats:sub>2<\/jats:sub>\n                    and enhances the catalytic activity of polysulfide conversion. The LSBs assembled using a P\u2010MoO\n                    <jats:sub>2\u2212x<\/jats:sub>\n                    \/NPC coated polypropylene separator display an initial discharge capacity of 1621 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and rate performance of 774 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 5 C. Even with a sulfur loading of 8.1\u00a0mg cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and lean electrolyte conditions, the cell achieves an initial areal capacity of 11.3 mAh cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at 0.1 C. This work provides a biopolymer nanofiber solution for constructing LSB separators with advanced electrochemical reactivity.\n                  <\/jats:p>","DOI":"10.1002\/adma.202419918","type":"journal-article","created":{"date-parts":[[2025,2,26]],"date-time":"2025-02-26T00:16:53Z","timestamp":1740529013000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":51,"title":["Nanocellulose\u2010Derived Hierarchical Carbon Framework\u2010Supported P\u2010Doped MoO\n                    <sub>2<\/sub>\n                    Nanoparticles for Optimizing Redox Kinetics in Lithium\u2013Sulfur Batteries"],"prefix":"10.1002","volume":"37","author":[{"given":"Mengjiao","family":"Shi","sequence":"first","affiliation":[{"name":"Key Laboratory of Bio\u2010Based Material Science and Technology of the Ministry of Education Northeast Forestry University  Harbin 150040 P. R. 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