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Among various carbon capture technologies, CO\n                    <jats:sub>2<\/jats:sub>\n                    membrane separation stands out for its simplicity and energy efficiency in applications including gas purification and industrial gas recovery. Herein, a series of fluorine\u2010tailored porous carbon molecular sieve (CMS) membranes derived from precisely designed precursors, achieving a well\u2010balanced high permeability and selectivity for CO\n                    <jats:sub>2<\/jats:sub>\n                    separation are developed. Incorporating bent terphenyl monomers and both aliphatic\/aromatic trifluoromethyl groups disrupted dense chain packing and promoted pore formation with enhanced permeability and selectivity for CO\n                    <jats:sub>2<\/jats:sub>\n                    separation. The\n                    <jats:bold>TFM\u2010550<\/jats:bold>\n                    membrane, derived from a fluorinated stretched polymer backbone precursor, exhibits exceptional performance with a CO\n                    <jats:sub>2<\/jats:sub>\n                    permeability of 47\u00a0190\u00a0\u00b1\u00a03204 Barrer and a CO\n                    <jats:sub>2<\/jats:sub>\n                    \/N\n                    <jats:sub>2<\/jats:sub>\n                    selectivity of 28.3\u00a0\u00b1\u00a05.7, while\n                    <jats:bold>TFM\u2010800<\/jats:bold>\n                    presented a higher selectivity of 71.8\u00a0\u00b1\u00a011.5, surpassing the 2019 upper bound. Furthermore, under flue gas conditions (CO\n                    <jats:sub>2<\/jats:sub>\n                    \/O\n                    <jats:sub>2<\/jats:sub>\n                    \/N\n                    <jats:sub>2<\/jats:sub>\n                    = 1\/1\/4 in molar ratio), the CMS membrane demonstrate high CO\n                    <jats:sub>2<\/jats:sub>\n                    permeability of 36,204\u00a0\u00b1\u00a02,235 Barrer and outstanding CO\n                    <jats:sub>2<\/jats:sub>\n                    \/N\n                    <jats:sub>2<\/jats:sub>\n                    selectivity of 35.3\u00a0\u00b1\u00a01.8. The results here highlight the effectiveness of fluorine tailoring and the potential of fluorinated CMS membranes for sustainable industrial carbon capture applications.\n                  <\/jats:p>","DOI":"10.1002\/adma.202420477","type":"journal-article","created":{"date-parts":[[2025,4,5]],"date-time":"2025-04-05T06:04:08Z","timestamp":1743833048000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":33,"title":["High\u2010Performance Carbon Capture with Fluorine\u2010Tailored Carbon Molecular Sieve Membranes"],"prefix":"10.1002","volume":"37","author":[{"given":"Shan","family":"Xu","sequence":"first","affiliation":[{"name":"School of Chemistry and Materials Science Hangzhou Institute for Advanced Study University of Chinese Academy of Sciences  1 Sub\u2010lane Xiangshan Hangzhou 310024 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Chemistry School of Science and Research Center for Industries of the Future Westlake University  Hangzhou 310030 China"},{"name":"Institute of Natural Sciences Westlake Institute for Advanced Study  Hangzhou 310024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-3542-0342","authenticated-orcid":false,"given":"Yunlong","family":"Ji","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science Hangzhou Institute for Advanced Study University of Chinese Academy of Sciences  1 Sub\u2010lane Xiangshan Hangzhou 310024 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