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Nowadays, the CTM value is still low as the area increases to larger than 100 cm<jats:sup>2<\/jats:sup>. In this work, the crucial role of solvent in CTM for printing, which on one side influenced the large area homogeneity due to the ink rheology property, and on the other side impacted phase separation dynamics because of vaporization and crystalline rate is highlighted. The films from TMB show excessive pure phase and printing line defects in vertical the printing direction due to slow volatilization speed and low adhesion, while Tol\u2010based films present printing line defects along the printing direction due to large surface adhesion are demonstrated. In contrast, the films from non\u2010halogenated solvent, o\u2010XY exhibited a suitable phase separation size and excellent large\u2010area homogeneity. Consequently, the fully printed 1\u00a0cm<jats:sup>2<\/jats:sup> FOSCs exhibit an efficiency of 14.81%. Moreover, the FOSCs module with an area of 28\u2013104\u00a0cm<jats:sup>2<\/jats:sup> gives an efficiency of over 13%, with a CTM of 0.9. Selecting suitable non\u2010halogenated solvents to achieve large\u2010area uniformity and appropriate phase separation morphology in &gt;100\u00a0cm<jats:sup>2<\/jats:sup> modules is of great importance for the industrialization of FOSCs.<\/jats:p>","DOI":"10.1002\/adma.202500115","type":"journal-article","created":{"date-parts":[[2025,3,17]],"date-time":"2025-03-17T06:30:41Z","timestamp":1742193041000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":39,"title":["High Cell to Module Efficiency Remaining Ratio of \u224890% for the 100\u00a0cm<sup>2<\/sup> Fully Roll\u2010to\u2010Roll Gravure Printed Flexible Organic Solar Cells From Non\u2010Halogenated Solvent"],"prefix":"10.1002","volume":"37","author":[{"given":"Shutao","family":"Yang","sequence":"first","affiliation":[{"name":"Henan Institutes of Advanced Technology Zhengzhou University  Zhengzhou 450052 P. R. 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