{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,14]],"date-time":"2026-07-14T14:07:18Z","timestamp":1784038038229,"version":"3.55.0"},"reference-count":39,"publisher":"Wiley","issue":"32","license":[{"start":{"date-parts":[[2025,6,4]],"date-time":"2025-06-04T00:00:00Z","timestamp":1748995200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100000266","name":"Engineering and Physical Sciences Research Council","doi-asserted-by":"publisher","award":["EP\/S030662\/1"],"award-info":[{"award-number":["EP\/S030662\/1"]}],"id":[{"id":"10.13039\/501100000266","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2025,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Coordination nanosheets (CONASHs) or conjugated metal organic frameworks (MOFs) with distinctive metal\u2010organic bonding structures exhibit promise for electronics, sensing, and energy storage. Porous Nickel\u2010Benzene hexathiol complex (Ni\u2010BHT) with noteworthy conductivity was first reported a decade ago, and recent synthetic modifications produced non\u2010porous Ni\u2010BHT with enhanced conductivity (\u224850 S cm<jats:sup>\u22121<\/jats:sup>). Here the charge transport physics of such non\u2010porous Ni\u2010BHT films are studied with even higher conductivity (\u2248112 S cm<jats:sup>\u22121<\/jats:sup>). In contrast to the thermally activated electrical conductivity, thermoelectric measurements suggest an intrinsic metallic nature of Ni\u2010BHT. It is shown that it is possible to tune the Fermi level and carrier polarity in Ni\u2010BHT by electrolyte gating; gating is initially governed by the formation of an interfacial, electric double layer and then evolves into an electrochemical (de)doping process. These findings not only contribute to a deeper understanding of charge transport in CONASHs, but also show that Fermi level tuning is an effective approach for enhancing the thermoelectric performance of CONASHs.<\/jats:p>","DOI":"10.1002\/adma.202500164","type":"journal-article","created":{"date-parts":[[2025,6,4]],"date-time":"2025-06-04T11:36:08Z","timestamp":1749036968000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Charge Transport and Carrier Polarity Tuning by Electrolyte Gating in Nickel Benzenehexathiol Coordination Nanosheets"],"prefix":"10.1002","volume":"37","author":[{"given":"Tian","family":"Wu","sequence":"first","affiliation":[{"name":"Cavendish Laboratory University of Cambridge  19 J J Thomson Avenue Cambridge CB3 0US UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinglong","family":"Ren","sequence":"additional","affiliation":[{"name":"Cavendish Laboratory University of Cambridge  19 J J Thomson Avenue Cambridge CB3 0US UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhengkang","family":"Qu","sequence":"additional","affiliation":[{"name":"Cavendish Laboratory University of Cambridge  19 J J Thomson Avenue Cambridge CB3 0US UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ian E.","family":"Jacobs","sequence":"additional","affiliation":[{"name":"Cavendish Laboratory University of Cambridge  19 J J Thomson Avenue Cambridge CB3 0US UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lu","family":"Zhang","sequence":"additional","affiliation":[{"name":"Cavendish Laboratory University of Cambridge  19 J J Thomson Avenue Cambridge CB3 0US UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Naoya","family":"Fukui","sequence":"additional","affiliation":[{"name":"Research Institute for Science and Technology Tokyo University of Science  2641 Yamazaki Noda\u2010shi Chiba\u2010ken 278\u20108510 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Materials Science &amp; Metallurgy University of Cambridge  27 Charles Babbage Road Cambridge CB3 0FS UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hiroshi","family":"Nishihara","sequence":"additional","affiliation":[{"name":"Research Institute for Science and Technology Tokyo University of Science  2641 Yamazaki Noda\u2010shi Chiba\u2010ken 278\u20108510 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9827-6061","authenticated-orcid":false,"given":"Henning","family":"Sirringhaus","sequence":"additional","affiliation":[{"name":"Cavendish Laboratory University of Cambridge  19 J J Thomson Avenue Cambridge CB3 0US UK"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,6,4]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-017-0044-5"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C1CS15092H"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2018.09.012"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2017.08.028"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b09600"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja308229p"},{"key":"e_1_2_8_7_1","first-page":"16","volume":"162","author":"Sheberla D.","year":"2016","journal-title":"Nat. Mater."},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja5116937"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja312380b"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja507619d"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202106204"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c10849"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201707568"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abf3996"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl401147u"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201202790"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-024-01953-6"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.2772781"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.add9627"},{"key":"e_1_2_8_20_1","first-page":"1189","volume":"35","author":"Emin D.","year":"1977","journal-title":"Philos. Mag. A J. Theor. Exp. Appl. Phys."},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1088\/0022-3719\/14\/28\/010"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1080\/095008396179995"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/sia.7296"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms8408"},{"key":"e_1_2_8_25_1","author":"Boris A. L. E.","year":"1984","journal-title":"Electron. Prop. Doped Semicond."},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms2213"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.31.44"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.50.5196"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/0379-6779(96)80013-0"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202312325"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adt9196"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.40.2806"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.91.066602"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.105.205104"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1088\/0034-4885\/79\/4\/046502"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-53786-1"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(99)00552-6"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.4867224"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.0c06181"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202500164","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T21:12:43Z","timestamp":1759785163000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202500164"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,6,4]]},"references-count":39,"journal-issue":{"issue":"32","published-print":{"date-parts":[[2025,8]]}},"alternative-id":["10.1002\/adma.202500164"],"URL":"https:\/\/doi.org\/10.1002\/adma.202500164","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,6,4]]},"assertion":[{"value":"2025-01-03","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-06-04","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2500164"}}