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It can be paired with several large\u2010scale cathode reactions that produce valuable chemical substances in an electrochemical cell. However, high\u2010performing and reliable 2e\u2010WOR anodic catalysts are yet to be fully developed. In this work, a rationally designed, inexpensive, robust, and selective graphite catalyst electrode is presented, made by following the key principle mechanisms of 2e\u2010WOR. First, an aerophilic graphite\u2010based electrode is created to leverage the challenges posed by the four\u2010electron WOR, where\u00a0the generated O\n                    <jats:sub>2<\/jats:sub>\n                    from this reaction is kept onto the electrode surface to shift the O intermediates binding on graphite in the direction of improved H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    generation. An initial improvement in H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    selectivity of seven fold is observed, albeit with no improved H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    generation rates. The stunted H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    generation is ascribed to poor activity from pristine graphite, courtesy of less active sites and low intrinsic O\n                    <jats:sub>2<\/jats:sub>\n                    binding in the electrolyte environment. Second, to improve and balance graphite's activity and selectivity, the structure of graphite is altered via different elemental doping (with N, S, B, and P atoms), a method that allows the retention of the O\n                    <jats:sub>2<\/jats:sub>\n                    on the graphite surface. The super\u2010aerophilic B\u2010doped graphite catalyst (optimum) reaches a maximum Faraday efficiency (FE) of 60.6 \u00b1 2.6% with a production rate of 26.7 \u00b1 0.6 \u00b5mol min\n                    <jats:sup>\u22121<\/jats:sup>\n                    cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    (85.9 \u00b1 2.2 mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    partial current density) and excellent stability of over 120 h. In tandem, cathodic H\n                    <jats:sub>2<\/jats:sub>\n                    co\u2010production is demonstrated with an FE of above 90%. This approach demonstrates a rational approach to designing inexpensive and robust 2e\u2010WOR anode catalysts for H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    and the possibility of its use in chemical co\u2010production at the cathode.\n                  <\/jats:p>","DOI":"10.1002\/adma.202500834","type":"journal-article","created":{"date-parts":[[2025,5,27]],"date-time":"2025-05-27T08:49:03Z","timestamp":1748335743000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":36,"title":["Water Oxidation to Hydrogen Peroxide Over a Super\u2010Aerophilic Graphite Catalyst"],"prefix":"10.1002","volume":"37","author":[{"given":"Umer","family":"Javed","sequence":"first","affiliation":[{"name":"UQ Dow Centre for Sustainable Engineering Innovation School of Chemical Engineering The University of Queensland  St Lucia Brisbane Queensland 4072 Australia"},{"name":"ARC Centre of Excellence for Green Electrochemical Transformation of Carbon Dioxide The University of Queensland  St. Lucia Brisbane Queensland 4072 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4243-6043","authenticated-orcid":false,"given":"Mike","family":"Tebyetekerwa","sequence":"additional","affiliation":[{"name":"UQ Dow Centre for Sustainable Engineering Innovation School of Chemical Engineering The University of Queensland  St Lucia Brisbane Queensland 4072 Australia"},{"name":"ARC Centre of Excellence for Green Electrochemical Transformation of Carbon Dioxide The University of Queensland  St. Lucia Brisbane Queensland 4072 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cheng","family":"Tang","sequence":"additional","affiliation":[{"name":"Materials Genome Institute Shanghai University  99 Shangda Road Shanghai 200444 P. 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