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Herein, the atomic design and control of golden single\u2010atom alloys (PdAu\n                    <jats:sub>1<\/jats:sub>\n                    and PtAu\n                    <jats:sub>1<\/jats:sub>\n                    SAAs) based on fully ordered PdBi and PtBi matrixes is presented, serving as highly selective, active, and stable cathode and anode electrocatalysts, respectively, to trigger direct methanol fuel cell (DMFC). The octahedral PdAu\n                    <jats:sub>1<\/jats:sub>\n                    SAA exhibits ultrahigh mass\u2010activity of 5.37 A mg\n                    <jats:sub>Pd + Au<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    without noticeable decay for 12\u00a00000 cycles toward oxygen reduction. While PdAu\n                    <jats:sub>1<\/jats:sub>\n                    SAA is inactive for methanol oxidation, PtAu\n                    <jats:sub>1<\/jats:sub>\n                    SAA exhibits an ultrahigh mass\u2010activity of 28.59 A mg\n                    <jats:sub>Pt + Au<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    . The selective electrocatalysts drive a practical DMFC with a high\u2010power density of 155.0\u00a0mW cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . Density functional theory calculations reveal the desired regulation of selectivity via reducing the energy barrier for potential\u2010determining steps (PDS) of\n                    <jats:sup>*<\/jats:sup>\n                    OH to H\n                    <jats:sub>2<\/jats:sub>\n                    O and\n                    <jats:sup>*<\/jats:sup>\n                    HCOO to CO\n                    <jats:sub>2<\/jats:sub>\n                    . This work provides a general strategy to engineer multimetallic alloys at the atomic level, advancing the development of high\u2010performance electrocatalysts.\n                  <\/jats:p>","DOI":"10.1002\/adma.202500848","type":"journal-article","created":{"date-parts":[[2025,5,27]],"date-time":"2025-05-27T08:49:03Z","timestamp":1748335743000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["Golden Single\u2010Atom Alloys Selectively Boosting Oxygen Reduction and Methanol Oxidation"],"prefix":"10.1002","volume":"37","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5756-119X","authenticated-orcid":false,"given":"Shuiping","family":"Luo","sequence":"first","affiliation":[{"name":"Shenzhen Key Laboratory of Energy Electrocatalytic Materials Guangdong Provincial Key Laboratory of New Energy Materials Service Safety College of Materials Science and Engineering Shenzhen University  Shenzhen Guangdong 518055 P. R. 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