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However, achieving high selectivity for methanol, especially at high current densities, remains challenging due to competing reactions that favor methane and hydrogen formation. Here, the tailored synthesis of Cu\/Cu\n                    <jats:sub>2<\/jats:sub>\n                    P\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>7<\/jats:sub>\n                    \u2010based hybrid catalysts is reported for efficient and selective methanol production through the discharge of lithium\u2010ion batteries. The catalyst exhibits a Faradaic efficiency exceeding 50% in both H\u2010cells and gas\u2010diffusion electrode cells, achieving one of the highest reported methanol partial current densities of over 100\u00a0mA\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . Experimental and computational analyses reveal a synergistic effect between Cu nanoparticles with a predominant (111) surface and Cu\n                    <jats:sub>2<\/jats:sub>\n                    P\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>7<\/jats:sub>\n                    nanoparticles, which enhances selective methanol production via the HCOOH intermediate pathway. These findings provide insights into designing cost\u2010effective electrocatalysts for selective methanol production.\n                  <\/jats:p>","DOI":"10.1002\/adma.202501021","type":"journal-article","created":{"date-parts":[[2025,5,21]],"date-time":"2025-05-21T01:56:03Z","timestamp":1747792563000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Selective Electrosynthesis of Methanol from CO\n                    <sub>2<\/sub>\n                    Over Cu\/Cu\n                    <sub>2<\/sub>\n                    P\n                    <sub>2<\/sub>\n                    O\n                    <sub>7<\/sub>\n                    Via the Formate Pathway"],"prefix":"10.1002","volume":"37","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1550-9745","authenticated-orcid":false,"given":"Hyunwoo","family":"Kim","sequence":"first","affiliation":[{"name":"School of Energy and Chemical Engineering Ulsan National 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