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However, it is challenging to balance the selectivity, capacity, and adsorption kinetics of the adsorbents. Herein, an efficient kinetic separation of acetylene and carbon dioxide is reported, which have nearly identical kinetic sizes, achieved through modification of the one\u2010dimensional (1D) channels of a micrometer\u2010sized mordenite. Under ambient conditions, the weak acid salt\u2010modified mordenite denoted as NaAlO\n                    <jats:sub>2<\/jats:sub>\n                    @MOR(0.5), exhibits a remarkable kinetic separation selectivity of 534.3 while retaining an excellent diffusivity for CO\n                    <jats:sub>2<\/jats:sub>\n                    . Compared to other adsorbent materials, its dynamic column performance for carbon dioxide significantly exceeds those of molecular sieve materials. In terms of separation selectivity, it is superior to thermodynamic separation adsorbents. The high efficiency of NaAlO\n                    <jats:sub>2<\/jats:sub>\n                    @MOR(0.5) in CO\n                    <jats:sub>2<\/jats:sub>\n                    \/C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    kinetic separation is validated by column breakthrough experiments. Furthermore, NaAlO\n                    <jats:sub>2<\/jats:sub>\n                    @MOR(0.5) has a low cost and high thermal stability. This study can guide the design of adsorbents that balance selectivity, capacity, and gas diffusivity, to provide a highly efficient kinetic separation of gas molecules with similar kinetic diameters.\n                  <\/jats:p>","DOI":"10.1002\/adma.202501870","type":"journal-article","created":{"date-parts":[[2025,5,27]],"date-time":"2025-05-27T08:49:03Z","timestamp":1748335743000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Efficient Kinetic Separation of Carbon Dioxide from Acetylene Using Mordenites Featuring Modified 1D Channels with Excellent Selectivity and Diffusion"],"prefix":"10.1002","volume":"37","author":[{"given":"Xianming","family":"Zhang","sequence":"first","affiliation":[{"name":"Zhejiang Key Laboratory of Intelligent Manufacturing for Functional Chemicals College of Chemical and Biological Engineering Zhejiang University  Hangzhou Zhejiang 310058 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Wang","sequence":"additional","affiliation":[{"name":"Zhejiang Key Laboratory of Intelligent Manufacturing for Functional Chemicals College of Chemical and Biological Engineering Zhejiang University  Hangzhou Zhejiang 310058 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lifeng","family":"Yang","sequence":"additional","affiliation":[{"name":"Zhejiang Key Laboratory of Intelligent Manufacturing for Functional Chemicals College of Chemical and Biological Engineering Zhejiang University  Hangzhou Zhejiang 310058 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaofei","family":"Lu","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Functional Materials Intelligent Manufacturing of Zhejiang Province ZJU\u2010Hangzhou Global Scientific and Technological Innovation Center  Hangzhou Zhejiang 310012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xian","family":"Suo","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Functional Materials Intelligent Manufacturing of Zhejiang Province ZJU\u2010Hangzhou Global Scientific and Technological Innovation Center  Hangzhou Zhejiang 310012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xili","family":"Cui","sequence":"additional","affiliation":[{"name":"Zhejiang Key Laboratory of Intelligent Manufacturing for Functional Chemicals College of Chemical and Biological Engineering Zhejiang University  Hangzhou Zhejiang 310058 China"},{"name":"Engineering Research Center of Functional Materials Intelligent Manufacturing of Zhejiang Province ZJU\u2010Hangzhou Global Scientific and Technological Innovation Center  Hangzhou Zhejiang 310012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7418-0046","authenticated-orcid":false,"given":"Huabin","family":"Xing","sequence":"additional","affiliation":[{"name":"Zhejiang Key Laboratory of Intelligent Manufacturing for Functional Chemicals College of Chemical and Biological Engineering Zhejiang University  Hangzhou Zhejiang 310058 China"},{"name":"Engineering Research Center of Functional Materials Intelligent Manufacturing of Zhejiang Province ZJU\u2010Hangzhou Global Scientific and Technological Innovation Center  Hangzhou Zhejiang 310012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,4,17]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201900058"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00756C"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/b802426j"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2023.215093"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.8b05431"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11705-022-2183-x"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201806732"},{"key":"e_1_2_8_8_1","first-page":"277","volume-title":"Ullmann's Encyclopedia of Industrial Chemistry","author":"P\u00e4ssler P.","year":"2011"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202100584"},{"key":"e_1_2_8_10_1","first-page":"6","volume":"61","author":"Cui J.","year":"2022","journal-title":"Angew. 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