{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T23:58:23Z","timestamp":1788220703576,"version":"build-2803163510"},"reference-count":46,"publisher":"Wiley","issue":"26","license":[{"start":{"date-parts":[[2025,4,8]],"date-time":"2025-04-08T00:00:00Z","timestamp":1744070400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,4,8]],"date-time":"2025-04-08T00:00:00Z","timestamp":1744070400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["2024BRB009"],"award-info":[{"award-number":["2024BRB009"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22275060"],"award-info":[{"award-number":["22275060"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100021171","name":"Basic and Applied Basic Research Foundation of Guangdong Province","doi-asserted-by":"publisher","award":["2023B1515120043"],"award-info":[{"award-number":["2023B1515120043"]}],"id":[{"id":"10.13039\/501100021171","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2025,7]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The selective CO\n                    <jats:sub>2<\/jats:sub>\n                    electroreduction (CO\n                    <jats:sub>2<\/jats:sub>\n                    R) toward specific C\n                    <jats:sub>2<\/jats:sub>\n                    products represents a critical challenge for practical applicability, requiring precise control over\n                    <jats:sup>*<\/jats:sup>\n                    CO intermediates. Herein, a \u201cpolymer\u2010halogen\u201d pocketed Cu catalyst is proposed, wherein the adjustable concentration of Iodide ion (I\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) within the pocket enables continuous modulation of\n                    <jats:sup>*<\/jats:sup>\n                    CO adsorption configurations on the Cu, thereby enabling tailored CO\n                    <jats:sub>2<\/jats:sub>\n                    R toward ethylene or ethanol production. A perfluorosulfonic acid (PFSA)\u2010modified CuI catalyst is constructed, where I\n                    <jats:sup>\u2212<\/jats:sup>\n                    is in situ leaching from CuI and subsequently confined by PFSA as an anion shielding layer to form polymer\u2010halogen pockets. By tuning the thickness of PFSA shell, the amount of I\n                    <jats:sup>\u2212<\/jats:sup>\n                    in the pocket can be controlled. The surface\u2010enhanced in situ Raman spectroscopy demonstrates that the coverage of\n                    <jats:sup>*<\/jats:sup>\n                    CO intermediates on Cu surface increases and tends to adsorb at low coordination Cu sites in catalyst granule for dimerization reaction as the I\n                    <jats:sup>\u2212<\/jats:sup>\n                    concentration in the pocket increases. Furthermore, the coordination environment exhibits distinct product selectivity.\n                    <jats:sup>*<\/jats:sup>\n                    CO at medium\u2010coordinated sites favor ethanol production, while those at low\u2010coordinated sites are conducive to ethylene formation. This strategy enables wide modulation of ethylene\u2010to\u2010ethanol ratios from 0.65 to 3.96, achieving peak Faradaic efficiencies (FE) of 60.3 \u00b1\u00a02.1% for ethylene and 48.3 \u00b1\u00a01.3% for ethanol.\n                  <\/jats:p>","DOI":"10.1002\/adma.202504292","type":"journal-article","created":{"date-parts":[[2025,4,9]],"date-time":"2025-04-09T02:18:56Z","timestamp":1744165136000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Polymer\u2010Halogen Pockets Steering\n                    <sup>*<\/sup>\n                    CO Adsorption Configurations for Highly Selective CO\n                    <sub>2<\/sub>\n                    Electroreduction"],"prefix":"10.1002","volume":"37","author":[{"given":"Mao","family":"Wu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Materials Processing and Die &amp; Mould Technology, and School of Materials Science and Engineering Huazhong University of Science and Technology  Wuhan Hubei 430074 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruoou","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials Processing and Die &amp; Mould Technology, and School of Materials Science and Engineering Huazhong University of Science and Technology  Wuhan Hubei 430074 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junyuan","family":"Duan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials Processing and Die &amp; Mould Technology, and School of Materials Science and Engineering Huazhong University of Science and Technology  Wuhan Hubei 430074 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shicheng","family":"Zhu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials Processing and Die &amp; Mould Technology, and School of Materials Science and Engineering Huazhong University of Science and Technology  Wuhan Hubei 430074 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bowen","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials Processing and Die &amp; Mould Technology, and School of Materials Science and Engineering Huazhong University of Science and Technology  Wuhan Hubei 430074 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhaoyang","family":"Shi","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials Processing and Die &amp; Mould Technology, and School of Materials Science and Engineering Huazhong University of Science and Technology  Wuhan Hubei 430074 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Youwen","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials Processing and Die &amp; Mould Technology, and School of Materials Science and Engineering Huazhong University of Science and Technology  Wuhan Hubei 430074 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huiqiao","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials Processing and Die &amp; Mould Technology, and School of Materials Science and Engineering Huazhong University of Science and Technology  Wuhan Hubei 430074 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bao Yu","family":"Xia","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Huazhong University of Science and Technology  Wuhan Hubei 430074 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0985-4806","authenticated-orcid":false,"given":"Tianyou","family":"Zhai","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials Processing and Die &amp; Mould Technology, and School of Materials Science and Engineering Huazhong University of Science and Technology  Wuhan Hubei 430074 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,4,8]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00705"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-019-0450-y"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-29699-2"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893-021-00739-x"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-023-00259-w"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-022-00880-6"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-019-0306-7"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-019-0383-7"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c01478"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202116706"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-024-01633-4"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-020-0450-0"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202414642"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c08748"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202413703"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC06035C"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b02217"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.140091"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2302851120"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202203896"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2407350121"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202319936"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-49247-4"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202114238"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE04147F"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-022-00840-0"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202102657"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9EE01341E"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c01190"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/celc.201901535"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2EE01334G"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202104114"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b03147"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b05532"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-51478-4"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-017-0009-x"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-07032-0"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c06697"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c03830"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/0927-0256(96)00008-0"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.54.11169"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.77.3865"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.3382344"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.21759"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.20291"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.464397"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202504292","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/adma.202504292","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202504292","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,4,8]],"date-time":"2026-04-08T10:39:00Z","timestamp":1775644740000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202504292"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,4,8]]},"references-count":46,"journal-issue":{"issue":"26","published-print":{"date-parts":[[2025,7]]}},"alternative-id":["10.1002\/adma.202504292"],"URL":"https:\/\/doi.org\/10.1002\/adma.202504292","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,4,8]]},"assertion":[{"value":"2025-03-04","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-04-08","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2504292"}}