{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T14:18:59Z","timestamp":1787062739650,"version":"build-2736575974"},"reference-count":76,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2025,9,24]],"date-time":"2025-09-24T00:00:00Z","timestamp":1758672000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2025,9,24]],"date-time":"2025-09-24T00:00:00Z","timestamp":1758672000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Vat photopolymerization (VP) is a powerful tool for the fabrication of architected ceramic and metal structures. However, conventional methods of ceramic\/metal VP, such as with the use of slurries or organic\u2013inorganic hybrid resins, have challenges with viscosities, light\u2010scattering, and limited material compositions. Recently, the use of metal\u2010salt solutions has emerged as a promising approach for the VP of ceramics and metals. While versatile and accessible, the process is accompanied by a significant amount of shrinkage, which causes warping, porosity, and structural damage. Here, a versatile method is presented for fabricating dense architected ceramics and metals with low conversion linear shrinkages. Central to this method is a post\u2010fabrication repeated infusion\u2010coprecipitation process that progressively\u00a0increases the metal loading in the 3D \u201cblank\u201d hydrogels. Thermal treatment of these high metal content hydrogels then converts them into ceramic or metal architectures. To demonstrate the versatility of this approach, a variety of 3D ceramic and metal structures with shrinkages as low as 20% while maintaining densities &gt;80% is fabricated. This infusion\u2010precipitation\u2010based process thus enables the VP of high\u2010quality ceramics and metals, which is necessary for the fabrication of advanced architected materials and devices.<\/jats:p>","DOI":"10.1002\/adma.202504951","type":"journal-article","created":{"date-parts":[[2025,9,24]],"date-time":"2025-09-24T12:53:29Z","timestamp":1758718409000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Hydrogel\u2010Based Vat Photopolymerization of Ceramics and Metals with Low Shrinkages via Repeated Infusion Precipitation"],"prefix":"10.1002","volume":"38","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0891-6462","authenticated-orcid":false,"given":"Yiming","family":"Ji","sequence":"first","affiliation":[{"name":"Institute of Electrical and Micro Engineering \u00c9cole Polytechnique F\u00e9d\u00e9rale de Lausanne (EPFL)  Rue de la Maladi\u00e8re 71b Neuch\u00e2tel 2000 Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6944-9146","authenticated-orcid":false,"given":"Ying","family":"Hong","sequence":"additional","affiliation":[{"name":"Institute of Electrical and Micro Engineering \u00c9cole Polytechnique F\u00e9d\u00e9rale de Lausanne (EPFL)  Rue de la Maladi\u00e8re 71b Neuch\u00e2tel 2000 Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-5112-7614","authenticated-orcid":false,"given":"Dhruv R.","family":"Bhandari","sequence":"additional","affiliation":[{"name":"Institute of Electrical and Micro Engineering \u00c9cole Polytechnique F\u00e9d\u00e9rale de Lausanne (EPFL)  Rue de la Maladi\u00e8re 71b Neuch\u00e2tel 2000 Switzerland"},{"name":"Department of Metallurgical Engineering &amp; Materials Science Indian Institute of Technology Bombay  Main Gate Rd, IIT Area, Powai Mumbai Maharashtra 400076 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4114-6167","authenticated-orcid":false,"given":"Daryl W.","family":"Yee","sequence":"additional","affiliation":[{"name":"Institute of Electrical and Micro Engineering \u00c9cole Polytechnique F\u00e9d\u00e9rale de Lausanne (EPFL)  Rue de la Maladi\u00e8re 71b Neuch\u00e2tel 2000 Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,9,24]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1146\/annurev-matsci-070115-031826"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1179\/1743280415Y.0000000008"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-48534-4"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2313962121"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.addma.2024.104113"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0203140"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.1c02851"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-024-01780-5"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtsust.2025.101086"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4YA00011K"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3SC06999K"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-47831-2"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41378-024-00692-7"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c05209"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abn0090"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-53513-w"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adk5556"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1557\/mrs.2019.234"},{"key":"e_1_2_8_19_1","doi-asserted-by":"crossref","unstructured":"F42 Committee n.d. https:\/\/doi.org\/10.1520\/F3177\u201021(access: June 2025).","DOI":"10.1520\/F3177"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202214211"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1364\/OME.538751"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40964-022-00336-0"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/pi.6165"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jeurceramsoc.2018.11.013"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.addma.2024.104156"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.addma.2024.104182"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-46929-x"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2024.04.348"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apmt.2022.101553"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dental.2019.02.001"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2023.12.274"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2023.01.085"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202307175"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pmatsci.2022.100969"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202102758"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.addma.2020.101366"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jeurceramsoc.2024.116812"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-03071-9"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1088\/1361-6463\/ac8d15"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202001675"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202406916"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202405487"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/admt.202000791"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jeurceramsoc.2024.116773"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-022-22444-1"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.156189"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201901345"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202101992"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/adem.202201927"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-022-05433-2"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202418035"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.3c02309"},{"key":"e_1_2_8_53_1","first-page":"4","volume":"17","author":"Waddell T.","year":"2024","journal-title":"Proc. SPIE"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40436-024-00514-z"},{"key":"e_1_2_8_55_1","unstructured":"A.Saigal S. J.Velling A.Dhawan M.Azcona Baez M.Nocum J. R.Greer inASME 2023 Aerospace Structures Structural Dynamics and Materials Conf. American Society Of Mechanical Engineers San Diego California USA2023 p.V001T03A007."},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202405135"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202405053"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202309313"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c07296"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja209245v"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmaterialslett.5c00407"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2RA06522C"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.eurpolymj.2022.111011"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.heliyon.2023.e14682"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jphotochem.2007.05.010"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ultramic.2021.113275"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5QI00139K"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2023.03.236"},{"key":"e_1_2_8_69_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jeurceramsoc.2020.05.079"},{"key":"e_1_2_8_70_1","doi-asserted-by":"publisher","DOI":"10.1039\/b103226g"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1089\/3dp.2018.0060"},{"key":"e_1_2_8_72_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-017-02267-9"},{"key":"e_1_2_8_73_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202402130"},{"key":"e_1_2_8_74_1","doi-asserted-by":"publisher","DOI":"10.3390\/met9070756"},{"key":"e_1_2_8_75_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtcomm.2020.101195"},{"key":"e_1_2_8_76_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202105144"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202504951","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/adma.202504951","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202504951","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T18:07:57Z","timestamp":1783015677000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202504951"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,9,24]]},"references-count":76,"journal-issue":{"issue":"8","published-print":{"date-parts":[[2026,2]]}},"alternative-id":["10.1002\/adma.202504951"],"URL":"https:\/\/doi.org\/10.1002\/adma.202504951","archive":["Portico"],"relation":{"has-preprint":[{"id-type":"doi","id":"10.26434\/chemrxiv-2025-vwjgv","asserted-by":"object"}]},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,9,24]]},"assertion":[{"value":"2025-03-13","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-09-24","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e04951"}}