{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T13:30:56Z","timestamp":1791725456032,"version":"4.3.4"},"reference-count":73,"publisher":"Wiley","issue":"41","license":[{"start":{"date-parts":[[2025,8,2]],"date-time":"2025-08-02T00:00:00Z","timestamp":1754092800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22278329"],"award-info":[{"award-number":["22278329"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["92472124"],"award-info":[{"award-number":["92472124"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100015401","name":"Key Research and Development Projects of Shaanxi Province","doi-asserted-by":"publisher","award":["2024PT\u2010ZCK\u201082"],"award-info":[{"award-number":["2024PT\u2010ZCK\u201082"]}],"id":[{"id":"10.13039\/501100015401","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2025,10]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Anode\u2010free lithium\u2010metal batteries, offer high energy density, but suffer from limited lifespan due to sluggish Li\n                    <jats:sup>+<\/jats:sup>\n                    desolvation at the anode. Conventional artificial layers on the anode attract Li\n                    <jats:sup>+<\/jats:sup>\n                    by polar groups, yet inadvertently accumulate solvent molecules near these polar layers, impede desolvation, and form an organic\u2010rich solid electrolyte interphase (SEI) with low ionic conductivity. Herein, a selective repulsion\u2010adsorption strategy is proposed, achieved using a layer (MS layer, 35\u00a0nm) comprising polystyrene sulfonic acid (PSS) and montmorillonite (MMT). During electrospray fabrication, the PSS self\u2010assemble, with non\u2010polar benzene rings and C\u2010H main chains facing outward, while the \u2010SO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    groups are buried underneath. The non\u2010polar components can repel polar solvent molecules, and negatively charged MMT will absorb Li\n                    <jats:sup>+<\/jats:sup>\n                    , suppressing solvent accumulation and facilitating desolvation. Meanwhile, the anions attracted by MMT will form an inorganic\u2010rich SEI with superior ionic conductivity. Furthermore, the PSS\u2010MMT interface forms a rapid Li\n                    <jats:sup>+<\/jats:sup>\n                    transport pathway with reduced migration barriers. Consequently, anode\u2010free MS\u2010Cu||LFP cells operate over 350 cycles, increasing \u2248200% compared with Cu||LFP cells. Additionally, 2 Ah anode\u2010free MS\u2010Cu||LFP (340\u00a0Wh kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and MS\u2010Cu||NCM811 pouch cells (490\u00a0Wh kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) maintain 80% capacity after 100 and 50 cycles. This work presents an efficient strategy to enhance Li\n                    <jats:sup>+<\/jats:sup>\n                    kinetics for high\u2010performance batteries.\n                  <\/jats:p>","DOI":"10.1002\/adma.202505520","type":"journal-article","created":{"date-parts":[[2025,8,2]],"date-time":"2025-08-02T08:13:11Z","timestamp":1754122391000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":26,"title":["Enhancing Li\n                    <sup>+<\/sup>\n                    Kinetics Via Selective Repulsion\u2010Adsorption and Intermolecular Ion\u2010Conduction Layers for High\u2010Energy\u2010Density Anode\u2010Free Lithium\u2010Metal Batteries"],"prefix":"10.1002","volume":"37","author":[{"given":"Chanqiao","family":"Zhao","sequence":"first","affiliation":[{"name":"School of Chemistry Engineering Research Center of Energy Storage Materials and Devices Ministry of Education State Key Laboratory of Electrical Insulation and Power Equipment Xi'an Jiaotong University Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Gao","sequence":"additional","affiliation":[{"name":"School of Chemistry Engineering Research Center of Energy Storage Materials and Devices Ministry of Education State Key Laboratory of Electrical Insulation and Power Equipment Xi'an Jiaotong University Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuzhi","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry Engineering Research Center of Energy Storage Materials and Devices Ministry of Education State Key Laboratory of Electrical Insulation and Power Equipment Xi'an Jiaotong University Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangkai","family":"Yin","sequence":"additional","affiliation":[{"name":"School of Chemistry Engineering Research Center of Energy Storage Materials and Devices Ministry of Education State Key Laboratory of Electrical Insulation and Power Equipment Xi'an Jiaotong University Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hong","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry Engineering Research Center of Energy Storage Materials and Devices Ministry of Education State Key Laboratory of Electrical Insulation and Power Equipment Xi'an Jiaotong University Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weiping","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemistry Engineering Research Center of Energy Storage Materials and Devices Ministry of Education State Key Laboratory of Electrical Insulation and Power Equipment Xi'an Jiaotong University Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaofei","family":"Hu","sequence":"additional","affiliation":[{"name":"School of Chemistry Engineering Research Center of Energy Storage Materials and Devices Ministry of Education State Key Laboratory of Electrical Insulation and Power Equipment Xi'an Jiaotong University Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiuhong","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry Engineering Research Center of Energy Storage Materials and Devices Ministry of Education State Key Laboratory of Electrical Insulation and Power Equipment Xi'an Jiaotong University Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kai","family":"Xi","sequence":"additional","affiliation":[{"name":"School of Chemistry Engineering Research Center of Energy Storage Materials and Devices Ministry of Education State Key Laboratory of Electrical Insulation and Power Equipment Xi'an Jiaotong University Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5683-0973","authenticated-orcid":false,"given":"Shujiang","family":"Ding","sequence":"additional","affiliation":[{"name":"School of Chemistry Engineering Research Center of Energy Storage Materials and Devices Ministry of Education State Key Laboratory of Electrical Insulation and Power Equipment Xi'an Jiaotong University Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8935-4689","authenticated-orcid":false,"given":"Wei","family":"Yu","sequence":"additional","affiliation":[{"name":"School of Chemistry Engineering Research Center of Energy Storage Materials and Devices Ministry of Education State Key Laboratory of Electrical Insulation and Power Equipment Xi'an Jiaotong University Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,8,2]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-021-00962-y"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202017063"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-29531-x"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202305386"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-024-01997-8"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201702296"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/aesr.202000102"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202108397"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-023-01252-5"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202301892"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202302647"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202311301"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202407648"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-48021-w"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3GC05027K"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202401114"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-21683-6"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202410818"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-020-0668-8"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202310358"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202405802"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202003709"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202304978"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-39673-1"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-021-00839-0"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.9b09551"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b11750"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202203912"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2023.03.017"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202209404"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2021.106490"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202401114"},{"key":"e_1_2_7_33_1","first-page":"69","volume":"2024","author":"Song Y. Z.","year":"2013","journal-title":"Sci. Bull."},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-020-00268-7"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-42512-y"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202400652"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202014241"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-022-01020-x"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202100537"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2021.10.033"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-022-00952-z"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2020.03.051"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-022-01107-2"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-024-01565-z"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202106047"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201906427"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202105962"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2023.09.004"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1038\/s42004-019-0234-0"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.1c03877"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202000804"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-020-0648-z"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2012.05.038"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.8b03148"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c09849"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2022.231941"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.1c02585"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA00419K"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/batt.202400505"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/admt.202301902"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c10258"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.esci.2023.100189"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201903466"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202001440"},{"key":"e_1_2_7_65_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2023.02.036"},{"key":"e_1_2_7_66_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.0c03015"},{"key":"e_1_2_7_67_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4TA04603J"},{"key":"e_1_2_7_68_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2024.234094"},{"key":"e_1_2_7_69_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2021.11.037"},{"key":"e_1_2_7_70_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-32794-z"},{"key":"e_1_2_7_71_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.0c08094"},{"key":"e_1_2_7_72_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mser.2018.07.001"},{"key":"e_1_2_7_73_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms2513"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202505520","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,17]],"date-time":"2025-10-17T07:22:55Z","timestamp":1760685775000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202505520"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,8,2]]},"references-count":73,"journal-issue":{"issue":"41","published-print":{"date-parts":[[2025,10]]}},"alternative-id":["10.1002\/adma.202505520"],"URL":"https:\/\/doi.org\/10.1002\/adma.202505520","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,8,2]]},"assertion":[{"value":"2025-03-22","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-08-02","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e05520"}}