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However, achieving high\u2010performance organic RTP remains challenging due to weak spin\u2010orbit coupling, rapid non\u2010radiative decay, and unstable triplet excitons. Early studies focused on crystal engineering, as ordered lattices restrict molecular motion and stabilize triplet excitons. Analyzing crystal structures and packing provides valuable insights into intermolecular interactions, while theoretical calculations have clarified electronic structures, laying the foundation for rational RTP material design. However, recent findings suggest RTP in many single\u2010component systems may arise from trace impurities, significantly influencing RTP properties. This discovery has greatly advanced the understanding of impurity\u2010induced phosphorescence. This review systematically examines the role of impurities in RTP, detailing their origins from starting materials, solvents, and side reactions. It also explores how these identified impurities can serve as essential building blocks for designing new RTP materials. Finally, essential methods for evaluating compound purity, emphasizing the critical importance of rigorous analysis and validation are presented. 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