{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T03:40:14Z","timestamp":1791862814186,"version":"4.3.4"},"reference-count":59,"publisher":"Wiley","issue":"33","license":[{"start":{"date-parts":[[2025,5,30]],"date-time":"2025-05-30T00:00:00Z","timestamp":1748563200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52025013"],"award-info":[{"award-number":["52025013"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22121005"],"award-info":[{"award-number":["22121005"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2025,8]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Replacing the kinetically sluggish oxygen evolution reaction with the thermodynamically favorable methanol oxidation reaction (MOR) represents a promising strategy for energy\u2010efficient hydrogen production. However, optimizing electrocatalytic performance in the coupled hydrogen evolution reaction (HER) and MOR requires precise regulation of the electrochemical coordination environment and a fundamental understanding of activity origins, posing a significant challenge. Here, a scalable strategy is developed that harnesses the high electronegativity of fluorine (F) to tailor the coordination environment of Ni\n                    <jats:sub>3<\/jats:sub>\n                    N, enhancing HER kinetics. Concurrently, adsorbed F\u00a0ions induce rapid and extensive self\u2010reconstruction of the Ni\n                    <jats:sub>3<\/jats:sub>\n                    N surface during MOR by dynamically modulating interfacial ion concentrations (OH\u207b and Ni species). This reconstruction enhances catalytic activity and enables the selective oxidation of methanol to formate via a sequential pathway, involving primary O\u2010H bond activation followed by subsequent C\u2010H bond cleavage at Ni active sites. Consequently, F\n                    <jats:sub>10<\/jats:sub>\n                    \u2010Ni\n                    <jats:sub>3<\/jats:sub>\n                    N demonstrates exceptional bifunctional performance, delivering 2.02\u00a0V and remarkable stability (600\u00a0h) for MOR\u2010coupled hydrogen production in a membrane electrode assembly\u2010based flow electrolyzer at an industrially relevant current density of 200\u00a0mA\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . This work establishes a dual\u2010regulation paradigm for electrocatalysts, offering mechanistic insights into surface reconstruction and a rational design framework for next\u2010generation energy conversion systems.\n                  <\/jats:p>","DOI":"10.1002\/adma.202507573","type":"journal-article","created":{"date-parts":[[2025,5,30]],"date-time":"2025-05-30T05:02:29Z","timestamp":1748581349000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":68,"title":["Tuning Surface Coordination Environment of Ni\n                    <sub>3<\/sub>\n                    N by Fluorine Modification for Efficient Methanol Electrooxidation Assisted Hydrogen Evolution"],"prefix":"10.1002","volume":"37","author":[{"given":"Hongye","family":"Qin","sequence":"first","affiliation":[{"name":"Frontiers Science Center for New Organic Matter Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) State Key Laboratory of Advanced Chemical Power Sources Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) College of Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinhong","family":"Li","sequence":"additional","affiliation":[{"name":"Frontiers Science Center for New Organic Matter Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) State Key Laboratory of Advanced Chemical Power Sources Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) College of Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guangliang","family":"Lin","sequence":"additional","affiliation":[{"name":"Frontiers Science Center for New Organic Matter Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) State Key Laboratory of Advanced Chemical Power Sources Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) College of Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kangnan","family":"Yuan","sequence":"additional","affiliation":[{"name":"Frontiers Science Center for New Organic Matter Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) State Key Laboratory of Advanced Chemical Power Sources Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) College of Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haocheng","family":"Yang","sequence":"additional","affiliation":[{"name":"Frontiers Science Center for New Organic Matter Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) State Key Laboratory of Advanced Chemical Power Sources Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) College of Chemistry Nankai University  Tianjin 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