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Despite extensive efforts to improve initial Coulombic efficiency (ICE) via electrochemical prelithiation, the fundamental processes governing transition metals (TMs) dissolution and associated degradation mechanisms in MOFs\u2010based full cells remain unclear. In this study, crystalline cobalt\u2010nickel bimetallic metal\u2010organic frameworks CoNi<jats:sub>x<\/jats:sub>\u2010MOF (CoNi<jats:sub>x<\/jats:sub>\u2010Benzene dicarboxylic MOFs), specifically derived from benzene dicarboxylic (BDC) ligands, are selected as the target material for investigation. A solid\u2010state corrosion (SSC) strategy for prelithiating MOFs anodes with corrosion of lithium metal is proposed for the first time. The full cell with prelithiated MOFs anode achieves an energy density of 493\u00a0Wh kg<jats:sup>\u22121<\/jats:sup> and demonstrates superior cycling stability with 83.3% capacity retention after 240 cycles at 0.2 C. The SSC prelithiation strategy effectively passivates Co\/Ni nanoparticles, reducing Ni dissolution percentage by an order of magnitude (from 15.32% to 1.16%), which is identified as the key factor underpinning the enhanced full cell performance. This study underscores the practical applicability of MOFs\u2010based anodes prelithiated by the SSC strategy for achieving high\u2010energy\u2010density and long\u2010cycling lithium\u2010ion batteries.<\/jats:p>","DOI":"10.1002\/adma.202507962","type":"journal-article","created":{"date-parts":[[2025,6,25]],"date-time":"2025-06-25T10:50:04Z","timestamp":1750848604000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Unlocking the Potential of MOFs Anodes via Solid\u2010State Corrosion Prelithiation for High\u2010Energy Li\u2010Ion Batteries"],"prefix":"10.1002","volume":"37","author":[{"given":"Huanhao","family":"Lei","sequence":"first","affiliation":[{"name":"Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Department of Chemistry College of Smart Materials and Future Energy Fudan University  Shanghai 200433 P. R. 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