{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T04:37:13Z","timestamp":1791866233091,"version":"4.3.4"},"reference-count":57,"publisher":"Wiley","issue":"44","license":[{"start":{"date-parts":[[2025,7,30]],"date-time":"2025-07-30T00:00:00Z","timestamp":1753833600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52405414"],"award-info":[{"award-number":["52405414"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["2024M762580"],"award-info":[{"award-number":["2024M762580"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2025,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Conventional packed\u2010bed catalysts suffer from single\u2010scale porosity, insufficient mechanical strength, and suboptimal mass transfer efficiency. Inspired by the fractal structure of the lung bronchi, a design and 3D printing method for gradient meta\u2010structural catalysts is proposed by integrating synthesized LaFe\n                    <jats:sub>0.5<\/jats:sub>\n                    Ni\n                    <jats:sub>0.5<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    (LFN) perovskite with pseudo\u2010boehmite, achieving ultralow pressure drop and high catalytic efficiency.\u00a0Computational fluid dynamics and reaction simulations guide the design of uniform and gradient\u2010structured catalysts with hierarchical woodpile channels (0.5\u20133\u00a0mm). Compared with homogeneous catalysts, the gradient design theoretically exhibits 1.5\u2010fold and 1.1\u2010fold increases in flow velocity and hydrogen production, respectively. Meta\u2010structural catalysts are fabricated with gradient multi\u2010peak pore distribution (9.32\u00a0nm, 103.75\u00a0nm) by regionally modulating unit cell sizes and LFN content (11\u201335%) combined with the dehydroxylation of pseudo\u2010boehmite. 3D\u2010printed perovskite catalysts demonstrate a 78.7\u2010fold increase in specific surface area (102.26 m\n                    <jats:sup>2<\/jats:sup>\n                    g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and compressive strength of 8.48\u00a0MPa. In dry reforming of methane (DRM) tests, it achieves 82.13% CH\n                    <jats:sub>4<\/jats:sub>\n                    conversion, and 9.69\u00a0mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    syngas yield, outperforming conventional powder\u2010packed beds by 10% efficiency. This study achieves mass transfer and catalytic performance coupling by tuning gradient hierarchical pores and tailoring flow dynamics, offering a paradigm for robust, high\u2010efficiency catalyst design across diverse applications.\n                  <\/jats:p>","DOI":"10.1002\/adma.202508078","type":"journal-article","created":{"date-parts":[[2025,7,30]],"date-time":"2025-07-30T07:16:18Z","timestamp":1753859778000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["3D\u2010Printed Bioinspired Meta\u2010Structural Perovskite Catalysts for Dry Reforming of CH\n                    <sub>4<\/sub>\n                    and CO\n                    <sub>2<\/sub>"],"prefix":"10.1002","volume":"37","author":[{"given":"Cunbao","family":"Huo","sequence":"first","affiliation":[{"name":"State Key Laboratory for Manufacturing Systems Engineering Xi'an Jiaotong University  No. 28 Xian Ning West Road Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuwang","family":"Wu","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Manufacturing Systems Engineering Xi'an Jiaotong University  No. 28 Xian Ning West Road Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rongjiang","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Chemical Engineering Xi'an Jiaotong University  No. 28 Xian Ning West Road Xi'an 710049 China"},{"name":"Xi'an Taijin New Energy &amp; Materials Sci\u2010Tech Co., Ltd.  No. 15 West Section of Xijin Road Xi'an 710021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiqiang","family":"Wu","sequence":"additional","affiliation":[{"name":"College of Chemical Engineering Xi'an Jiaotong University  No. 28 Xian Ning West Road Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9618-3272","authenticated-orcid":false,"given":"Xiaoyong","family":"Tian","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Manufacturing Systems Engineering Xi'an Jiaotong University  No. 28 Xian Ning West Road Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Tan","sequence":"additional","affiliation":[{"name":"College of Chemical Engineering Xi'an Jiaotong University  No. 28 Xian Ning West Road Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kexin","family":"Li","sequence":"additional","affiliation":[{"name":"College of Chemical Engineering Xi'an Jiaotong University  No. 28 Xian Ning West Road Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yao","family":"Yang","sequence":"additional","affiliation":[{"name":"Lanzhou Petrochemical Research Center Petrochemical Research Institute PetroChina Company Limited  No.1 Heshui North Road Lanzhou 730060 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Baojie","family":"Wang","sequence":"additional","affiliation":[{"name":"Lanzhou Petrochemical Research Center Petrochemical Research Institute PetroChina Company Limited  No.1 Heshui North Road Lanzhou 730060 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhun","family":"Hu","sequence":"additional","affiliation":[{"name":"College of Chemical Engineering Xi'an Jiaotong University  No. 28 Xian Ning West Road Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lingling","family":"Wu","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Manufacturing Systems Engineering Xi'an Jiaotong University  No. 28 Xian Ning West Road Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dichen","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Manufacturing Systems Engineering Xi'an Jiaotong University  No. 28 Xian Ning West Road Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,7,30]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aav5077"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2023.126114"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aah7161"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2020.119328"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2018.04.072"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201915140"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c04643"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b05154"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c01386"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2017.10.022"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.enconman.2020.112507"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA05122E"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120778"},{"key":"e_1_2_8_14_1","first-page":"310","author":"De Vos Y.","year":"2024","journal-title":"Mater. Sci. Eng. B"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00060"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matdes.2019.108377"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202204751"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201603390"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.3389\/fceng.2022.834547"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202405334"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202311627"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201701134"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202302912"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jeurceramsoc.2021.02.016"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.3c00553"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.addma.2024.103983"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwaa251"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00797G"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-46337-1"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2021.04.019"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.201700401"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202107795"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202405835"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202308137"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.145504"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.123211"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202314204"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202406132"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202404794"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202213715"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abn0090"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202313986"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202312263"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202411951"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/admi.202201734"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jeurceramsoc.2022.04.048"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1116\/1.1247774"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-019-02779-7"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2005.03.036"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201901963"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120816"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2016.08.024"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2022.07.028"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.enconman.2022.115496"},{"key":"e_1_2_8_55_1","volume":"20","author":"Liu Y.","journal-title":"Small."},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c03098"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.123010"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202508078","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,11,7]],"date-time":"2025-11-07T07:00:23Z","timestamp":1762498823000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202508078"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,7,30]]},"references-count":57,"journal-issue":{"issue":"44","published-print":{"date-parts":[[2025,11]]}},"alternative-id":["10.1002\/adma.202508078"],"URL":"https:\/\/doi.org\/10.1002\/adma.202508078","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,7,30]]},"assertion":[{"value":"2025-04-29","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-07-30","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2508078"}}