{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T05:11:42Z","timestamp":1792041102454,"version":"4.4.0"},"reference-count":68,"publisher":"Wiley","issue":"41","license":[{"start":{"date-parts":[[2025,7,26]],"date-time":"2025-07-26T00:00:00Z","timestamp":1753488000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2023YFC3905002"],"award-info":[{"award-number":["2023YFC3905002"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22175071"],"award-info":[{"award-number":["22175071"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2025,10]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Electrocatalytic nitrate reduction reaction (NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    RR) in water offers a sustainable alternative for robust electrosynthesis of value\u2010added ammonia (NH\n                    <jats:sub>3<\/jats:sub>\n                    ) in ambient conditions. However, NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    RR electrocatalysis generally involves two\u2010step tandem routes and suffers from sluggish hydrodeoxygenation kinetics, which result in a low ammonia selectivity and yield rate. In this work, it is demonstrated that the high\u2010entropy effect of mesoporous metal oxides remarkably decreases the energy barrier of the hydrodeoxygenation route and facilitates two\u2010step tandem electrocatalysis of NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    RR, which thus promotes selective NH\n                    <jats:sub>3<\/jats:sub>\n                    electrosynthesis in an alkaline condition. By comparing a series of high\u2010entropy mesoporous metal oxides and corresponding metal alloys and monometallic counterparts, high\u2010entropy mesoporous (CoMnFeNiCu)\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    discloses the highest electrocatalytic performance for efficient NH\n                    <jats:sub>3<\/jats:sub>\n                    electrosynthesis from NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    RR, including remarkable NH\n                    <jats:sub>3<\/jats:sub>\n                    Faradaic efficiency of 96.3%, high NH\n                    <jats:sub>3<\/jats:sub>\n                    yield rate of 1.83 mmol h\n                    <jats:sup>\u22121<\/jats:sup>\n                    mg\n                    <jats:sup>\u22121<\/jats:sup>\n                    , and excellent recycling stability of 20 cycles, representing one of the best electrocatalysts reported in the past three years. Moreover, cathode NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    RR performance for selective NH\n                    <jats:sub>3<\/jats:sub>\n                    electrosynthesis is enhanced when further coupled with the thermodynamically favorable benzyl alcohol oxidation reaction at the anode. It is expected that the high\u2010entropy effect opens up a new route to design a library of novel tandem mesoporous metal electrocatalysts for the selective electrosynthesis of various valuable chemicals from wastewater.\n                  <\/jats:p>","DOI":"10.1002\/adma.202508982","type":"journal-article","created":{"date-parts":[[2025,7,26]],"date-time":"2025-07-26T13:15:18Z","timestamp":1753535718000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":45,"title":["High\u2010Entropy Effect of Mesoporous Metal Oxides Promotes Tandem Catalysis for Efficient Ammonia Electrosynthesis from Nitrate"],"prefix":"10.1002","volume":"37","author":[{"given":"Hangjuan","family":"He","sequence":"first","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology of Ministry of Education College of Chemistry Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huiqin","family":"Yao","sequence":"additional","affiliation":[{"name":"School of Basic Medical Sciences Ningxia Medical University  Yinchuan 750004 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lizhi","family":"Sun","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology of Ministry of Education College of Chemistry Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuyang","family":"Yang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology of Ministry of Education College of Chemistry Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhen\u2010An","family":"Qiao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry Jilin University  Changchun 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1305-5900","authenticated-orcid":false,"given":"Ben","family":"Liu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology of Ministry of Education College of Chemistry Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,7,26]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2021.152233"},{"key":"e_1_2_7_1_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.watres.2020.115962"},{"key":"e_1_2_7_1_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2021.149909"},{"key":"e_1_2_7_1_4","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202503291"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00857A"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202217071"},{"key":"e_1_2_7_2_3","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.3c10936"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.149769"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-45534-2"},{"key":"e_1_2_7_3_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202416910"},{"key":"e_1_2_7_3_4","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-48035-4"},{"key":"e_1_2_7_3_5","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202405179"},{"key":"e_1_2_7_3_6","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202312746"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-35533-6"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2024.124609"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2024.124528"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202217337"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c07061"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202401287"},{"key":"e_1_2_7_6_3","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-50670-w"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c00879"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-023-00951-2"},{"key":"e_1_2_7_7_3","volume":"13","author":"Sun L.","year":"2023","journal-title":"Adv. Energy Mater."},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201801538"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c18547"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-024-00602-5"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202504275"},{"key":"e_1_2_7_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202203219"},{"key":"e_1_2_7_9_4","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.ads3926"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-024-00690-7"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abg1600"},{"key":"e_1_2_7_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202423765"},{"key":"e_1_2_7_10_4","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202501886"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-024-00654-5"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2025.104295"},{"key":"e_1_2_7_11_3","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-58448-4"},{"key":"e_1_2_7_11_4","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202416111"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-44261-4"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202209242"},{"key":"e_1_2_7_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202420752"},{"key":"e_1_2_7_12_4","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-58495-x"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-50721-2"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.1c01242"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41524-022-00766-y"},{"key":"e_1_2_7_14_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2018.12.015"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja504407e"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.6b02645"},{"key":"e_1_2_7_15_3","doi-asserted-by":"publisher","DOI":"10.1039\/D4CS00484A"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c06904"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202500287"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202418344"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c07089"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.141960"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3696"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.121983"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c00418"},{"key":"e_1_2_7_20_3","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202207305"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202218717"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja071330n"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202202952"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202402767"},{"key":"e_1_2_7_22_3","volume":"10","author":"Qin J.","year":"2025","journal-title":"Catal. Sci. Technol."},{"key":"e_1_2_7_22_4","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-23390-8"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202400206"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE00784K"},{"key":"e_1_2_7_23_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202423112"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c01455"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202413560"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202508982","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,17]],"date-time":"2025-10-17T07:19:25Z","timestamp":1760685565000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202508982"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,7,26]]},"references-count":68,"journal-issue":{"issue":"41","published-print":{"date-parts":[[2025,10]]}},"alternative-id":["10.1002\/adma.202508982"],"URL":"https:\/\/doi.org\/10.1002\/adma.202508982","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,7,26]]},"assertion":[{"value":"2025-05-12","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-07-26","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e08982"}}