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However, the rational design of Cu(I)\u2010based halide scintillators remains challenging due to insufficient theoretical frameworks elucidating their structure\u2010property correlations. In this work, two Cu(I)\u2010based hybrid metal halides, Cu\n                    <jats:sub>2<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    \u2010IC (Ionic compound) are designed and Cu\n                    <jats:sub>4<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    \u2010CC (Coordination compound) via bonding mode control engineering. The Cu\n                    <jats:sub>2<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    \u2010IC exhibits blue emission, and the Cu\n                    <jats:sub>4<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    \u2010CC exhibits yellow emission, and the photoluminescence quantum yield (PLQY) of Cu\n                    <jats:sub>2<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    \u2010IC and Cu\n                    <jats:sub>2<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    \u2010IC are 91% and 100% respectively. The non\u2010radiative transitions are reduced due to the high rigidity of Cu\n                    <jats:sub>4<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    , resulting in a light yield up to 67\u00a0500 photons MeV\n                    <jats:sup>\u22121<\/jats:sup>\n                    and a detection limit as low as 47.3 nGy s\n                    <jats:sup>\u22121<\/jats:sup>\n                    of Cu\n                    <jats:sub>4<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    \u2010CC. Additionally, a high\u2010performance scintillator hydrogel based on Cu\n                    <jats:sub>4<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    \u2010CC with polyvinyl alcohol (PVA),H\n                    <jats:sub>2<\/jats:sub>\n                    O and dimethyl sulfoxide (DMSO)\u00a0is innovatively developed. Owing to the high transmittance, the large\u2010area scintillator hydrogel film (10 \u00d7 10 cm\n                    <jats:sup>2<\/jats:sup>\n                    ) achieves an X\u2010ray imaging resolution of 14 lp mm\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Furthermore, the synergistic effects of hydrogen bonding and coordination bonding endow the hydrogel scintillator with excellent plasticity and flexible stretchability.\u00a0The Cu\n                    <jats:sub>4<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    \u2010CC@PVA hydrogel proves promising for X\u2010ray imaging with excellent stability in harsh environments, matching state\u2010of\u2010the\u2010art scintillators.\n                  <\/jats:p>","DOI":"10.1002\/adma.202509478","type":"journal-article","created":{"date-parts":[[2025,7,31]],"date-time":"2025-07-31T12:08:40Z","timestamp":1753963720000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":36,"title":["Single Organic Cation Engineering Cu(I)\u2010Based Ionic and Coordinate Type Halides as High\u2010Efficiency Hydrogel Scintillator"],"prefix":"10.1002","volume":"37","author":[{"given":"Tianrui","family":"Li","sequence":"first","affiliation":[{"name":"Key Laboratory for Biobased Materials and Energy of Ministry of Education College of Materials and Energy South China Agricultural University  Guangzhou 510642 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Baoling","family":"Tang","sequence":"additional","affiliation":[{"name":"Key Laboratory for Biobased Materials and Energy of Ministry of Education College of Materials and Energy South China Agricultural University  Guangzhou 510642 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiance","family":"Jin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques Guangdong Engineering Technology Research and Development Center of Special Optical Fiber Materials and Devices School of Physics and Optoelectronics South China University of Technology  Guangzhou 510641 P. R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hailian","family":"Zhao","sequence":"additional","affiliation":[{"name":"Key Laboratory for Biobased Materials and Energy of Ministry of Education College of Materials and Energy South China Agricultural University  Guangzhou 510642 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuejie","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory for Biobased Materials and Energy of Ministry of Education College of Materials and Energy South China Agricultural University  Guangzhou 510642 P. R. 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