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Direct flue gas conversion can address the emissions from hard\u2010to\u2010abate sectors, including cement, steel, and power generation industries. Such integration with SCO\n                    <jats:sub>2<\/jats:sub>\n                    RR can also decarbonize the petrochemical industry and eliminate separation and purification steps. Here, recent progress and emerging opportunities for transformative flue\u2010gas\u2010tolerant systems for producing fuels and chemicals are reviewed. The review begins by analyzing recent progress in direct flue gas conversion and highlighting emerging micro\u2010reaction environment features. Next, performance degradation mechanisms associated with flue gas conversion in CO\n                    <jats:sub>2<\/jats:sub>\n                    RR systems are discussed. Following this, the bicarbonate reduction reaction (BRR) and CO\n                    <jats:sub>2<\/jats:sub>\n                    RR from amine\u2010based capture as emerging strategies for high\u2010rate, selective, and stable electrosynthesis of chemicals from feeds containing low CO\n                    <jats:sub>2<\/jats:sub>\n                    concentrations are highlighted. Finally, the mitigation of flue gas impurities such as oxygen, sulfur oxides, and nitrogen oxides, is discussed,\u00a0and perspectives for emerging opportunities are shared.\n                  <\/jats:p>","DOI":"10.1002\/adma.202509581","type":"journal-article","created":{"date-parts":[[2025,9,3]],"date-time":"2025-09-03T10:40:29Z","timestamp":1756896029000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["From Pollution to Value: Electrochemical Systems for Transforming Flue Gas into Chemicals and Fuels"],"prefix":"10.1002","volume":"37","author":[{"given":"Meng","family":"Wang","sequence":"first","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering National University of Singapore  Singapore 117585 Republic of Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Adnan","family":"Ozden","sequence":"additional","affiliation":[{"name":"Department of Mechanical and Nuclear 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