{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,18]],"date-time":"2026-10-18T14:14:28Z","timestamp":1792332868974,"version":"4.4.0"},"reference-count":87,"publisher":"Wiley","issue":"38","license":[{"start":{"date-parts":[[2025,6,27]],"date-time":"2025-06-27T00:00:00Z","timestamp":1750982400000},"content-version":"am","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"},{"start":{"date-parts":[[2025,6,27]],"date-time":"2025-06-27T00:00:00Z","timestamp":1750982400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52371230"],"award-info":[{"award-number":["52371230"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52271222"],"award-info":[{"award-number":["52271222"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22179080"],"award-info":[{"award-number":["22179080"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100007219","name":"Natural Science Foundation of Shanghai Municipality","doi-asserted-by":"publisher","award":["22ZR1443900"],"award-info":[{"award-number":["22ZR1443900"]}],"id":[{"id":"10.13039\/100007219","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2023YFB250400"],"award-info":[{"award-number":["2023YFB250400"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000923","name":"Australian Research Council","doi-asserted-by":"publisher","award":["FL210100050"],"award-info":[{"award-number":["FL210100050"]}],"id":[{"id":"10.13039\/501100000923","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000923","name":"Australian Research Council","doi-asserted-by":"publisher","award":["FT230100598"],"award-info":[{"award-number":["FT230100598"]}],"id":[{"id":"10.13039\/501100000923","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003399","name":"Science and Technology Commission of Shanghai Municipality","doi-asserted-by":"publisher","award":["21010503100"],"award-info":[{"award-number":["21010503100"]}],"id":[{"id":"10.13039\/501100003399","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003399","name":"Science and Technology Commission of Shanghai Municipality","doi-asserted-by":"publisher","award":["23DZ1202500"],"award-info":[{"award-number":["23DZ1202500"]}],"id":[{"id":"10.13039\/501100003399","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2025,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Ultrathin solid\u2010polymer\u2010electrolytes (SPEs) are the most promising alternative substituting for the conventional liquid electrolyte to enable high\u2010energy\u2010density, safe lithium\u2010metal\u2010batteries (LMBs). Nevertheless, developing ultrathin SPEs with both high ionic conductivity, and strong Li dendrite retardant is still a significant challenge. Here a scalable fabrication of high\u2010performance ultrathin (\u22487.8\u00a0\u00b5m) polycarbonate\u2010based electrolyte (UPCE) is proposed via electrolyte structural engineering, phase separation\u2010derived poly(vinylidene fluoride\u2010co\u2010hexafluoropropylene) (PVH) porous scaffold, without use of additional liquid additives. The rational electrolyte structural modulation with 1\u2010fluoro\u20104\u2010(1\u2010methylethenyl)benzene (FMB) enables a weakened Li\n                    <jats:sup>+<\/jats:sup>\n                    \u2010polymer interaction due to weak Li\n                    <jats:sup>+<\/jats:sup>\n                    solvation with fluorine, benzene ring, facilitates the formation of LiF\u2010rich solid\u2010electrolyte\u2010interphase on Li metal surface. As a result, the designed UPCE delivers a high ionic conductivity of 4.8 \u00d7 10\n                    <jats:sup>\u22124<\/jats:sup>\n                    S cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    , an ultrahigh critical current density of 11.5\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at 25\u00a0\u00b0C. The solid\u2010state Li symmetric cell attains unprecedented ultralong cycling over 6000\u00a0h at 0.5\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . Furthermore, the Li|LiCoO\n                    <jats:sub>2<\/jats:sub>\n                    cell cycles stably over 1500 cycles at a high operating voltage of 4.5\u00a0V, and the pouch cell can achieve a high energy density of 495\u00a0Wh kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    excluding the packaging. This work offers a new pathway inspiring efforts to commercialize ultrathin SPEs for high\u2010energy solid\u2010state LMBs.\n                  <\/jats:p>","DOI":"10.1002\/adma.202510376","type":"journal-article","created":{"date-parts":[[2025,6,27]],"date-time":"2025-06-27T09:57:34Z","timestamp":1751018254000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":71,"title":["Ultrathin Polymer Electrolyte With Fast Ion Transport and Stable Interface for Practical Solid\u2010state Lithium Metal Batteries"],"prefix":"10.1002","volume":"37","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5255-0739","authenticated-orcid":false,"given":"Shuixin","family":"Xia","sequence":"first","affiliation":[{"name":"School of Materials and Chemistry University of Shanghai for Science and Technology  Shanghai 200093 China"},{"name":"School of Chemical Engineering The University of Adelaide  Adelaide SA 5005 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangfeng","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Materials and Chemistry University of Shanghai for Science and Technology  Shanghai 200093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zongyan","family":"Jiang","sequence":"additional","affiliation":[{"name":"School of Materials and Chemistry University of Shanghai for Science and Technology  Shanghai 200093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoyan","family":"Wu","sequence":"additional","affiliation":[{"name":"School of Physical Science and Technology ShanghaiTech University  Shanghai 201210 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jodie A.","family":"Yuwono","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering The University of Adelaide  Adelaide SA 5005 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenrui","family":"Li","sequence":"additional","affiliation":[{"name":"School of Materials and Chemistry University of Shanghai for Science and Technology  Shanghai 200093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cheng","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering The University of Adelaide  Adelaide SA 5005 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gemeng","family":"Liang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering The University of Adelaide  Adelaide SA 5005 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingnan","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering The University of Adelaide  Adelaide SA 5005 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fangli","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering The University of Adelaide  Adelaide SA 5005 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Yu","sequence":"additional","affiliation":[{"name":"School of Physical Science and Technology ShanghaiTech University  Shanghai 201210 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yong","family":"Jiang","sequence":"additional","affiliation":[{"name":"School of Environmental and Chemical Engineering Shanghai University  Shanghai 200444 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianfeng","family":"Mao","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering The University of Adelaide  Adelaide SA 5005 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shiyou","family":"Zheng","sequence":"additional","affiliation":[{"name":"School of Materials and Chemistry University of Shanghai for Science and Technology  Shanghai 200093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3464-5301","authenticated-orcid":false,"given":"Zaiping","family":"Guo","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering The University of Adelaide  Adelaide SA 5005 Australia"},{"name":"Department of Materials Science and Engineering City University of Hong Kong  Kowloon Hong Kong 999077 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,6,27]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00636B"},{"key":"e_1_2_8_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202500077"},{"key":"e_1_2_8_1_3","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202100684"},{"key":"e_1_2_8_1_4","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c05040"},{"key":"e_1_2_8_1_5","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202409327"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2016.103"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2018.11.013"},{"key":"e_1_2_8_2_3","doi-asserted-by":"publisher","DOI":"10.1038\/nenergy.2017.35"},{"key":"e_1_2_8_2_4","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.4c02840"},{"key":"e_1_2_8_2_5","doi-asserted-by":"publisher","DOI":"10.1002\/cnl2.188"},{"key":"e_1_2_8_2_6","doi-asserted-by":"publisher","DOI":"10.1016\/j.esci.2022.02.008"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-019-0465-3"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202105329"},{"key":"e_1_2_8_3_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.esci.2022.03.001"},{"key":"e_1_2_8_3_4","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202103720"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-019-0431-3"},{"key":"e_1_2_8_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4821"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c15771"},{"key":"e_1_2_8_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202101168"},{"key":"e_1_2_8_5_3","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.4c04164"},{"key":"e_1_2_8_5_4","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c00990"},{"key":"e_1_2_8_5_5","doi-asserted-by":"publisher","DOI":"10.1002\/cnl2.130"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201800703"},{"key":"e_1_2_8_6_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-40609-y"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c09062"},{"key":"e_1_2_8_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202402625"},{"key":"e_1_2_8_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/sus2.70004"},{"key":"e_1_2_8_7_4","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2025.104129"},{"key":"e_1_2_8_7_5","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202303940"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-022-05627-8"},{"key":"e_1_2_8_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202100935"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-37997-6"},{"key":"e_1_2_8_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2021.12.004"},{"key":"e_1_2_8_9_3","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c12094"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202002741"},{"key":"e_1_2_8_10_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-023-01443-0"},{"key":"e_1_2_8_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/advs.201802353"},{"key":"e_1_2_8_10_4","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2025.104105"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202400115"},{"key":"e_1_2_8_11_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-35857-x"},{"key":"e_1_2_8_11_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202411224"},{"key":"e_1_2_8_11_4","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-49713-z"},{"key":"e_1_2_8_11_5","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202409489"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.129542"},{"key":"e_1_2_8_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2006.02.038"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202105329"},{"key":"e_1_2_8_13_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1600422113"},{"key":"e_1_2_8_13_3","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-019-0465-3"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202000831"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202304339"},{"key":"e_1_2_8_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202200368"},{"key":"e_1_2_8_15_3","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-41808-3"},{"key":"e_1_2_8_15_4","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202308309"},{"key":"e_1_2_8_15_5","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202302587"},{"key":"e_1_2_8_15_6","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202202143"},{"key":"e_1_2_8_15_7","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-023-01341-2"},{"key":"e_1_2_8_15_8","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202304164"},{"key":"e_1_2_8_15_9","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202203281"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202302559"},{"key":"e_1_2_8_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202314306"},{"key":"e_1_2_8_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202002545"},{"key":"e_1_2_8_16_4","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2022.107104"},{"key":"e_1_2_8_16_5","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202307142"},{"key":"e_1_2_8_16_6","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202104009"},{"key":"e_1_2_8_16_7","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202403078"},{"key":"e_1_2_8_16_8","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202401909"},{"key":"e_1_2_8_16_9","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-45372-2"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.0c00251"},{"key":"e_1_2_8_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2020.11.038"},{"key":"e_1_2_8_17_3","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202310395"},{"key":"e_1_2_8_17_4","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202311633"},{"key":"e_1_2_8_17_5","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202301470"},{"key":"e_1_2_8_17_6","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-023-01722-x"},{"key":"e_1_2_8_17_7","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-023-01279-8"},{"key":"e_1_2_8_17_8","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.1c02261"},{"key":"e_1_2_8_17_9","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-023-06653-w"},{"key":"e_1_2_8_17_10","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-024-01389-2"},{"key":"e_1_2_8_17_11","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2023.103124"},{"key":"e_1_2_8_17_12","doi-asserted-by":"publisher","DOI":"10.1039\/D2EE02904A"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202400303"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-018-0183-2"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.464913"},{"key":"e_1_2_8_20_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.37.785"},{"key":"e_1_2_8_20_3","doi-asserted-by":"publisher","DOI":"10.1063\/1.3382344"},{"key":"e_1_2_8_21_1","unstructured":"M. J.Frisch G. W.Trucks H. B.Schlegel G. E.Scuseria M. A.Robb J. R.Cheeseman G.Scalmani V.Barone G. A.Petersson H.Nakatsuji X.Li M.Caricato A. V.Marenich J.Bloino B. G.Janesko R.Gomperts B.Mennucci H. P.Hratchian J. V.Ortiz A. F.Izmaylov J. L.Sonnenberg D.Williams\u2010Young F.Ding F.Lipparini F.Egidi J.Goings B.Peng A.Petrone T.Henderson D.Ranasinghe et\u00a0al. Gaussian Inc. Wallingford CT2016."},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja9621760"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1093\/nar\/gkx312"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202510376","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202510376","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T07:01:00Z","timestamp":1759734060000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202510376"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,6,27]]},"references-count":87,"journal-issue":{"issue":"38","published-print":{"date-parts":[[2025,9]]}},"alternative-id":["10.1002\/adma.202510376"],"URL":"https:\/\/doi.org\/10.1002\/adma.202510376","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,6,27]]},"assertion":[{"value":"2025-06-02","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-06-27","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2510376"}}