{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,3]],"date-time":"2026-11-03T17:24:30Z","timestamp":1793726670423,"version":"4.6.1"},"reference-count":68,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2025,9,15]],"date-time":"2025-09-15T00:00:00Z","timestamp":1757894400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22071112"],"award-info":[{"award-number":["22071112"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22275098"],"award-info":[{"award-number":["22275098"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["62288102"],"award-info":[{"award-number":["62288102"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22302097"],"award-info":[{"award-number":["22302097"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFB3612600"],"award-info":[{"award-number":["2024YFB3612600"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,1]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The electrochemical reduction of CO\n                    <jats:sub>2<\/jats:sub>\n                    to methanol (CH\n                    <jats:sub>3<\/jats:sub>\n                    OH) offers a highly promising avenue for zero\u2010emission carbon recycling and renewable energy storage. However, achieving high CH\n                    <jats:sub>3<\/jats:sub>\n                    OH selectivity and long\u2010term stability in catalysts remains rare, presenting central challenges on the path to their commercialization. It is emerging to make multiscale design of metal centers of active sites and their surrounding environments under the crucial mechanism of pathway selection. Herein, the gridized nanomolecular and nanopolymer catalysts are reported for high effective electroreduction of CO\n                    <jats:sub>2<\/jats:sub>\n                    to CH\n                    <jats:sub>3<\/jats:sub>\n                    OH. An A\u2010type nanogrid (AG) and its organic nanopolymers with atomically dispersed iron (Fe) are well identified with the unique catalytic active sites of Fe\u2010N\n                    <jats:sub>1<\/jats:sub>\n                    C\n                    <jats:sub>3<\/jats:sub>\n                    Cl\n                    <jats:sub>1<\/jats:sub>\n                    . Notably, Fe\u2010based AG nanopolymer (FePAG) catalyst exhibits a CH\n                    <jats:sub>3<\/jats:sub>\n                    OH Faradaic efficiency of 60.5%, a CH\n                    <jats:sub>3<\/jats:sub>\n                    OH selectivity of 98.3%, and a stability of up to 100 h, outperforming currently reported molecular catalysts. The superior selectivity is probably attributed to the cooperation between the stronger *CO adsorption and the super\u2010hindrance that suppresses aggregates to guarantee the dispersion of single active sites. This study provides new insights in the exploration of nanomolecular and nanopolymer catalysis.\n                  <\/jats:p>","DOI":"10.1002\/adma.202511233","type":"journal-article","created":{"date-parts":[[2025,9,15]],"date-time":"2025-09-15T13:00:39Z","timestamp":1757941239000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Gridized Nanopolymer Catalysis with Atomically Dispersed Iron Achieves the Nearly 100% Selective Electrosynthesis of Methanol From CO\n                    <sub>2<\/sub>"],"prefix":"10.1002","volume":"38","author":[{"given":"Tonglin","family":"Yang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fangqi","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tao","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weihao","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fu","family":"Deng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunxiao","family":"Zhong","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qian","family":"Peng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zheng","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Feng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoyan","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"},{"name":"Frontiers Science Center for Flexible Electronics (FSCFE) MIIT Key Laboratory of Flexible Electronics (KLoFE) Northwestern Polytechnical University  Xi'an 710072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kuande","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chong","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Zhou","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuanzhao","family":"Lu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Pollution Control and Resource Reuse State Key Laboratory of Analytical Chemistry for Life Science the Frontiers Science Center for Critical Earth Material Cycling School of the Environment School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6110-993X","authenticated-orcid":false,"given":"Wenlei","family":"Zhu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Pollution Control and Resource Reuse State Key Laboratory of Analytical Chemistry for Life Science the Frontiers Science Center for Critical Earth Material Cycling School of the Environment School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying","family":"Wei","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Linghai","family":"Xie","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"},{"name":"Frontiers Science Center for Flexible Electronics (FSCFE) MIIT Key Laboratory of Flexible Electronics (KLoFE) Northwestern Polytechnical University  Xi'an 710072 China"},{"name":"School of Flexible Electronics (SoFE) and Henan Institute of Flexible Electronics (HIFE) Henan University  Zhengzhou 450046 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Huang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  9 Wenyuan Road Nanjing 210023 China"},{"name":"Frontiers Science Center for Flexible Electronics (FSCFE) MIIT Key Laboratory of Flexible Electronics (KLoFE) Northwestern Polytechnical University  Xi'an 710072 China"},{"name":"School of Flexible Electronics (SoFE) and Henan Institute of Flexible Electronics (HIFE) Henan University  Zhengzhou 450046 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,9,15]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature11475"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-021-00704-z"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-022-05540-0"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CS00857F"},{"key":"e_1_2_7_5_1","volume":"2","author":"Chen J. M.","year":"2021","journal-title":"Innovation"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-023-5653-7"},{"key":"e_1_2_7_7_1","volume":"6","author":"Li X.","year":"2025","journal-title":"Innovation"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-35450-8"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-022-00887-z"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-29698-3"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202108635"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-021-00289-y"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2023.215081"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-020-0610-2"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9EE03660A"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.9b00496"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aax4608"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaw7515"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1224581"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00218F"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-019-1760-8"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202310037"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-11868-5"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-52168-x"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201909257"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-023-01005-3"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202310623"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-39153-6"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c05961"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c08922"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-025-01866-8"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202502644"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-018-0010-1"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.1c00200"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c04957"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c07613"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19110440303"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.34133\/2022\/9820585"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202302664"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-48130-6"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-15401-x"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-49247-4"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202319936"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/smo.20240004"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/smo.20240024"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202014556"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202408013"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202208132"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-44586-0"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.201800241"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202111733"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202502221"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202205372"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202113895"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2020.119096"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201909257"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.0c03534"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202110303"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c02465"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c02411"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-024-01197-2"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202304007"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202306726"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202419550"},{"key":"e_1_2_7_65_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202312239"},{"key":"e_1_2_7_66_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c04935"},{"key":"e_1_2_7_67_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4QI01234H"},{"key":"e_1_2_7_68_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic00087a038"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202511233","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,1,3]],"date-time":"2026-01-03T06:28:38Z","timestamp":1767421718000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202511233"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,9,15]]},"references-count":68,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2026,1]]}},"alternative-id":["10.1002\/adma.202511233"],"URL":"https:\/\/doi.org\/10.1002\/adma.202511233","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,9,15]]},"assertion":[{"value":"2025-06-15","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-09-15","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e11233"}}