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This study demonstrates efficient electrochemical oxidation of PPCPs using a novel tin\u2010antimony doped carbon nanofiber membrane (Sn\u2010Sb\u2010CNF) anode leveraging dual\u2010metal synergy. Oxygen vacancies generated through this synergistic effect function as active sites, enhancing pollutant adsorption capacity and oxidant activation capability. The degradation mechanism proceeds primarily via dominant hydroxyl radical (\n                    <jats:sup>\u2022<\/jats:sup>\n                    OH) generation, leading to complete contaminant mineralization. Notably, Sn\/Sb dual\u2010metal doping modulates the electronic structure, altering the d\u2010band center from \u22124.777 to \u22122.175 eV and significantly lowering reaction energy barriers. This electronic optimization facilitates electron transfer kinetics and accelerates pollutant degradation. Owing to this synergy, the Sn\u2010Sb\u2010CNF anode achieved high removal efficiencies (&gt;90%) within 30 min for multiple PPCPs: ofloxacin (95%), enrofloxacin (91%), carbamazepine (90%), acetaminophen (82%), and ibuprofen (96%). Furthermore, the membrane exhibits potent antimicrobial activity, achieving 4\u2010log inactivation of tetracycline\u2010resistant\n                    <jats:italic>Escherichia coli<\/jats:italic>\n                    and 5\u2010log reduction of T7 bacteriophage within 30 min. In real wastewater containing antibiotic\u2010resistant bacteria from a treatment plant, the system attained 62% mineralization rate. This work establishes a dual\u2010metal synergy strategy that provides new avenues for efficient PPCP elimination in complex aqueous matrices.\n                  <\/jats:p>","DOI":"10.1002\/adma.202512066","type":"journal-article","created":{"date-parts":[[2025,9,12]],"date-time":"2025-09-12T11:59:17Z","timestamp":1757678357000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Dual\u2010Metal Synergy in Sn\u2010Sb\u2010CNF Membrane Anodes Boosts Electro\u2010Filtration Oxidation of Emerging Contaminants"],"prefix":"10.1002","volume":"38","author":[{"given":"Ruiquan","family":"Yu","sequence":"first","affiliation":[{"name":"Shenzhen Engineering Research Laboratory for Sludge and Food Waste Treatment and Resource Recovery Tsinghua Shenzhen International Graduate School Tsinghua University  Shenzhen 518055 China"},{"name":"Tsinghua Shenzhen International Graduate School Tsinghua University  Shenzhen 518055 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