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Here this study reports nonprecious metal\u2010based high\u2010entropy alloy\/intermetallic compound heterostructure with a 3D nanoporous architecture as a high\u2010performance electrocatalyst for hydrazine oxidation reaction. By making use of strain engineering of hexagonal close\u2010packed multicomponent intermetallic compound core, high\u2010entropy NiFeCoCuCrMn alloy surface is comprised of multiple active centers with undulatory adsorption energies, which enable *N\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    intermediate spillover to adjust rate\u2010determining step and lower kinetic barriers. As a consequence of nanoporous architecture endowing abundant multiple active surfaces, this heterostructure mediates hydrazine electrooxidation of as high as ampere\u2010level current densities at &gt;0.08\u00a0V versus reversible hydrogen electrode, showing genuine potential to replace sluggish oxygen evolution reaction for hydrogen production via water electrolysis. Its hydrazine oxidation\u2010assisted water electrolyser delivers 500\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at ultralow cell voltage of 0.87\u00a0V, and maintains exceptional stability for 1000 h.\n                  <\/jats:p>","DOI":"10.1002\/adma.202512081","type":"journal-article","created":{"date-parts":[[2025,8,25]],"date-time":"2025-08-25T10:05:17Z","timestamp":1756116317000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":36,"title":["High\u2010Entropy Alloy\/Intermetallic Compound Heterostructures for Efficient Hydrazine Oxidation\u2010Assisted Hydrogen Production"],"prefix":"10.1002","volume":"37","author":[{"given":"Hang","family":"Shi","sequence":"first","affiliation":[{"name":"Key Laboratory of Automobile Materials (Jilin University) Ministry of Education School of Materials Science and Engineering Jilin University  Changchun 130022 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