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Current purification technologies remain great challenges due to the unsatisfactory energy\u2010intensive, time\u2010consuming and noticeably costly reasons. Herein, a bifunctional electrocatalysts of Pd single\u2010atoms doped Cu\n                    <jats:sub>3<\/jats:sub>\n                    P quantum dots (Pd\u2010Cu\n                    <jats:sub>3<\/jats:sub>\n                    P SA\u2010QDs) are reported to moderately optimize the H* sorption behaviors for accelerating the kinetics of nitrate reduction (NO\n                    <jats:sub>3<\/jats:sub>\n                    RR) and formaldehyde oxidation (FOR) reactions in a dual\u2010directional way, thus realizing the high activity and selectivity for both cathodic ammonia (NH\n                    <jats:sub>3<\/jats:sub>\n                    ) synthesis and anodic H\n                    <jats:sub>2<\/jats:sub>\n                    production concurrently. Specifically, a very positive onset potential of +0.36 V (versus RHE) is recorded for NO\n                    <jats:sub>3<\/jats:sub>\n                    RR with a high faradaic efficiency (FE) of 99 % for NH\n                    <jats:sub>3<\/jats:sub>\n                    at \u22120.3V (versus RHE), while the FOR can be initialized at a very low onset potential of \u22120.07 V (versus RHE) with &gt; 90 % FE for formate and &gt; 95 % FE for H\n                    <jats:sub>2<\/jats:sub>\n                    at 0.3 V (versus RHE). Notably, a self\u2010powered galvanic system can be triggered by integrating the above two electrode\u2010based reactions, thus exhibiting an open\u2010circuit voltage of 0.892 V, a peak power density of 12.1 mW cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , and capable of generating 8.8 KWh kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    of electrical energy.\n                  <\/jats:p>","DOI":"10.1002\/adma.202512332","type":"journal-article","created":{"date-parts":[[2025,8,26]],"date-time":"2025-08-26T08:21:46Z","timestamp":1756196506000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":33,"title":["Pd Single\u2010Atoms Doped Cu\n                    <sub>3<\/sub>\n                    P Quantum Dots with Moderately Optimized H* Sorption Behaviors for Actualizing the Multifunctional \u201cFormaldehyde\u2010Nitrate\u201d Galvanic System"],"prefix":"10.1002","volume":"37","author":[{"given":"Rida","family":"Javed","sequence":"first","affiliation":[{"name":"College of Civil and Transportation Engineering Shenzhen Key Laboratory of Energy Electrocatalytic Materials Guangdong Provincial Key Laboratory of New Energy Materials Service Safety College of Materials Science and Engineering Shenzhen University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6206-2018","authenticated-orcid":false,"given":"Bin","family":"Zhao","sequence":"additional","affiliation":[{"name":"College of Civil and Transportation Engineering Shenzhen Key Laboratory of Energy Electrocatalytic Materials Guangdong Provincial Key Laboratory of New Energy Materials Service Safety College of Materials Science and Engineering Shenzhen University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zulakha","family":"Zafar","sequence":"additional","affiliation":[{"name":"College of Civil and Transportation Engineering Shenzhen Key Laboratory of Energy Electrocatalytic Materials Guangdong Provincial Key Laboratory of New Energy Materials Service Safety College of Materials Science and Engineering Shenzhen University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qianqian","family":"Zhao","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering University of Alberta  9211\u2010116 Street NW Edmonton Alberta T6G 1H9 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Arunpandiyan","family":"Surulinathan","sequence":"additional","affiliation":[{"name":"College of Civil and Transportation Engineering Shenzhen Key Laboratory of Energy Electrocatalytic Materials Guangdong Provincial Key Laboratory of New Energy Materials Service Safety College of Materials Science and Engineering Shenzhen University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ning","family":"Chen","sequence":"additional","affiliation":[{"name":"Canadian Light Source Inc.  Saskatoon Saskatchewan S7N 0X4 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Renfei","family":"Feng","sequence":"additional","affiliation":[{"name":"Canadian Light Source Inc.  Saskatoon Saskatchewan S7N 0X4 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Zhang","sequence":"additional","affiliation":[{"name":"Instrumental Analysis Center of Shenzhen University (Lihu Campus) Shenzhen University  Shenzhen Guangdong 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xian\u2010Zhu","family":"Fu","sequence":"additional","affiliation":[{"name":"College of Civil and Transportation Engineering Shenzhen Key Laboratory of Energy Electrocatalytic Materials Guangdong Provincial Key Laboratory of New Energy Materials Service Safety College of Materials Science and Engineering Shenzhen University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2465-7280","authenticated-orcid":false,"given":"Jing\u2010Li","family":"Luo","sequence":"additional","affiliation":[{"name":"College of Civil and Transportation Engineering Shenzhen Key Laboratory of Energy Electrocatalytic Materials Guangdong Provincial Key Laboratory of New Energy Materials Service Safety College of Materials Science and Engineering Shenzhen University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,8,26]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-022-05481-8"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.214280"},{"key":"e_1_2_7_3_1","first-page":"123","volume":"54","author":"Zha L.","year":"2021","journal-title":"Mater"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2022.130755"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202318989"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2009.06.005"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2019.122065"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-023-00951-2"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-40174-4"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-43179-1"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c00418"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-022-01121-4"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b13347"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3QM00734K"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202300390"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202105322"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c13740"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA07119J"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00408"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.2c03731"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.bej.2007.05.005"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.122774"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.58.2043"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2022.12.008"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-36142-7"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-022-00953-y"},{"key":"e_1_2_7_27_1","author":"Hu F.","year":"2025","journal-title":"Angew. 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