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However, such solvents typically result in suboptimal efficiency due to excessive molecular aggregation and unfavorable phase separation. To address this issue, an innovative anti\u2010solvent (AS) strategy is proposed that accelerates photovoltaic material precipitation by timed introduction of orthogonal solvents to reduce solvent solubility and enhance volatilization, thereby avoiding prolonged aggregation. The resulting optimized phase separation and fibrous morphology facilitate exciton dissociation and charge utilization, enabling PM6:D18:L8BO\u2010X\u2010based OSCs to achieve a remarkable efficiency of 20.51% (certified as 20.12%), significantly higher than that of the conventional\n                    <jats:italic>o<\/jats:italic>\n                    \u2010xylene\u2010processed devices. The AS strategy also exhibits broad universality, with notable efficiency gains across diverse photovoltaic materials and solvent systems. Furthermore, scaling the AS strategy to methanol soaking for large\u2010area fabrication yields a record module efficiency of 17.23%, which is one of the optimal performances reported for OSC modules with active areas exceeding 10.0\u00a0cm\n                    <jats:sup>2<\/jats:sup>\n                    . This work not only provides a practical solution for high\u2010efficiency, eco\u2010friendly OSC fabrication but also opens up new possibilities for their industrial\u2010scale deployment.\n                  <\/jats:p>","DOI":"10.1002\/adma.202514076","type":"journal-article","created":{"date-parts":[[2025,10,17]],"date-time":"2025-10-17T07:41:33Z","timestamp":1760686893000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":27,"title":["Over 20.5% Efficiency of Halogen\u2010Free Solvent\u2010Processed Organic Solar Cells Achieved by Anti\u2010Solvent Strategy"],"prefix":"10.1002","volume":"38","author":[{"given":"Xiaopeng","family":"Duan","sequence":"first","affiliation":[{"name":"Hangzhou International Innovation Institute Beihang University  Hangzhou 311115 P. R. China"},{"name":"School of Chemistry Beihang University  Beijing 100191 P. R. 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