{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T22:24:29Z","timestamp":1792794269781,"version":"4.5.0"},"reference-count":59,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2025,12,22]],"date-time":"2025-12-22T00:00:00Z","timestamp":1766361600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2025,12,22]],"date-time":"2025-12-22T00:00:00Z","timestamp":1766361600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,2]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Zirconium\u2010based metal\u2010organic frameworks (Zr\u2010MOFs) feature exceptional thermal\/chemical stability among various MOFs, enabling diverse applications. Their material properties are highly dependent on molecular structures consisting of Zr\u2010clusters and organic linkers. However, structural diversity in Zr\u2010MOFs remains constrained by the limited variety of known Zr\u2010clusters and the predominance of high\u2010symmetry linkers, which stems from the inherent symmetry constraints presented by Zr\u2010clusters. In this work, we develop a linker\u2010desymmetrization\u2010modulator\u2010compensation (LDMC) strategy to construct Zr\u2010MOFs with enhanced structural diversity. This approach reduces linker symmetry to create structural defects in Zr\u2010clusters, while such a thermodynamically unfavorable process can be compensated for by the coordination of modulators, such as benzoic acid and formic acid. As a result, two MOFs, PCN\u20101005 and PCN\u20101006, with unprecedented Zr\u2010clusters have been constructed. PCN\u20101005 features an asymmetric Zr\n                    <jats:sub>6<\/jats:sub>\n                    cluster stabilized by mono\u2010 and capping benzoates. In PCN\u20101006, a rare pentacarboxylate linker enables the formation of a dual\u2010node network comprised of both Zr\n                    <jats:sub>6<\/jats:sub>\n                    and Zr\n                    <jats:sub>6<\/jats:sub>\n                    \u2010f\u2010Zr\n                    <jats:sub>6<\/jats:sub>\n                    clusters, resulting in one\u2010dimensional channels with exceptional adsorption performance for methane and carbon dioxide, affording high selectivity over hydrogen. These findings underscore the advancement of the LDMC strategy in promoting the structural complexity and functionality of Zr\u2010MOFs, providing a versatile platform for energy and environmental applications.\n                  <\/jats:p>","DOI":"10.1002\/adma.202514373","type":"journal-article","created":{"date-parts":[[2025,12,23]],"date-time":"2025-12-23T07:05:24Z","timestamp":1766473524000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Structural Exploration of Zirconium Metal\u2013Organic Frameworks Through Linker Desymmetrization and Modulator Compensation"],"prefix":"10.1002","volume":"38","author":[{"given":"Rong\u2010Ran","family":"Liang","sequence":"first","affiliation":[{"name":"Department of Chemistry Texas A&amp;M University  College Station Texas USA"},{"name":"School of Energy and Environment Southeast University  Nanjing Jiangsu 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