{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T15:45:38Z","timestamp":1791819938303,"version":"4.3.4"},"reference-count":64,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2025,11,5]],"date-time":"2025-11-05T00:00:00Z","timestamp":1762300800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,11,5]],"date-time":"2025-11-05T00:00:00Z","timestamp":1762300800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2023YFB4006200"],"award-info":[{"award-number":["2023YFB4006200"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["92472121"],"award-info":[{"award-number":["92472121"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22502004"],"award-info":[{"award-number":["22502004"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,1]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The sluggish kinetics and catalyst poisoning of the ammonia oxidation reaction (AOR) pose technical barriers to adopting ammonia as a distributable carrier for green hydrogen and electricity. Herein, a class of PtIrRh nanowires (NWs, \u22481 nm diameter) is report with abundant terraces and oxyphilic doping for enhanced AOR electrocatalysis. It is first unravel, through size\u2010dependent AOR activity, that well\u2010coordinated terraces outperform under\u2010coordinated steps on platinum, guiding the rational design of 1D architecture. The compositionally\u2010optimized Pt\n                    <jats:sub>86<\/jats:sub>\n                    Ir\n                    <jats:sub>5<\/jats:sub>\n                    Rh\n                    <jats:sub>9<\/jats:sub>\n                    NWs achieve a mass activity of 324 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    <jats:sub>PGM<\/jats:sub>\n                    at 0.6 V, alongside an on\u2010set potential (\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>on\u2010set<\/jats:sub>\n                    ) of 0.41 V. Electrochemical studies coupling in situ attenuated total reflection Fourier transform infrared spectra establish voltammetry\u2010accessible descriptors: surface oxyphilicity governs the\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>on\u2010set<\/jats:sub>\n                    , while nitrogenous adsorption strength dictates peak current density (\n                    <jats:italic>j<\/jats:italic>\n                    <jats:sub>peak<\/jats:sub>\n                    ). In a membrane electrode assembly, the Pt\n                    <jats:sub>86<\/jats:sub>\n                    Ir\n                    <jats:sub>5<\/jats:sub>\n                    Rh\n                    <jats:sub>9<\/jats:sub>\n                    NWs enable ammonia electrolysis at 1 A cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    with a cell voltage of 0.63 V\u20141 V lower than the typical value of water electrolysis, and drive a direct ammonia fuel cell to 339 mW cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at 0.4 V. The findings redefine Pt\u2010based AOR catalyst design and advance ammonia\u2010mediated hydrogen economy toward practicality.\n                  <\/jats:p>","DOI":"10.1002\/adma.202514467","type":"journal-article","created":{"date-parts":[[2025,11,5]],"date-time":"2025-11-05T14:41:07Z","timestamp":1762353667000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Terracing Oxyphilic Platinum Sustains High\u2010Rate Ammonia Electrolysis and Fuel Cells"],"prefix":"10.1002","volume":"38","author":[{"given":"Xueda","family":"Ding","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering Peking University No.5 Yiheyuan Road, Haidian District Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zehong","family":"Yin","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University No.5 Yiheyuan Road, Haidian District Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yangkai","family":"Han","sequence":"additional","affiliation":[{"name":"Dalian Institute of Chemical Physics Chinese Academy of Sciences No.457 Zhongshan Road Dalian 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nan\u2010Nan","family":"Liang","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University No.5 Yiheyuan Road, Haidian District Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Song","family":"Lei","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering Tsinghua University No.30 Shuangqing Road, Haidian District Beijing 100084 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tingting","family":"Mao","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University No.5 Yiheyuan Road, Haidian District Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingrui","family":"Han","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University No.5 Yiheyuan Road, Haidian District Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenhe","family":"Yu","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University No.5 Yiheyuan Road, Haidian District Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying","family":"Ji","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University No.5 Yiheyuan Road, Haidian District Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junyi","family":"Li","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University No.5 Yiheyuan Road, Haidian District Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hengshuo","family":"Huang","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University No.5 Yiheyuan Road, Haidian District Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Wei","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University No.5 Yiheyuan Road, Haidian District Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yilin","family":"Zhao","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University No.5 Yiheyuan Road, Haidian District Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Teng","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University No.5 Yiheyuan Road, Haidian District Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jialei","family":"Huang","sequence":"additional","affiliation":[{"name":"School of Chemical and Biomolecular Engineering and ARC Centre of Excellence for Green Electrochemical Transformation of Carbon Dioxide The University of Sydney New South Wales Sydney NSW 2006 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zichang","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University No.5 Yiheyuan Road, Haidian District Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yun","family":"Zhao","sequence":"additional","affiliation":[{"name":"Dalian Institute of Chemical Physics Chinese Academy of Sciences No.457 Zhongshan Road Dalian 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fengwang","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemical and Biomolecular Engineering and ARC Centre of Excellence for Green Electrochemical Transformation of Carbon Dioxide The University of Sydney New South Wales Sydney NSW 2006 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9772-2154","authenticated-orcid":false,"given":"Mingchuan","family":"Luo","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University No.5 Yiheyuan Road, Haidian District Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,11,5]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-024-07322-2"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-024-01684-7"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-024-01644-1"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-023-00309-3"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-023-00321-7"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-021-00797-w"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2020.04.004"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2019.07.005"},{"key":"e_1_2_7_9_1","unstructured":"Ammonia Technology Roadmap (US Department of Energy) 2021."},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2022.05.096"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2024.01.065"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0191815jes"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE02467A"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2009.03.018"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-52499-9"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2017.01.020"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c15489"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2007.06.015"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.checat.2024.100932"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE03351K"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c05185"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-36322-5"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202418691"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c13451"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202306204"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202110702"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201200586"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl2017459"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/c4cp00260a"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c04626"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-42514-w"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202206178"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1088\/1361-6528\/ac893b"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201703460"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.1c03805"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp9120589"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/cs200681x"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c04876"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/B709809J"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/la501109g"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0131816jes"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-52684-w"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202304515"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c17605"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.enchem.2022.100093"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.5b02556"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c08228"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c02487"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jelechem.2018.02.047"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.4c00133"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201805833"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b00108"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893-023-01101-z"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2016.10.020"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202505616"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp2081148"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jelechem.2006.01.009"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-0728(01)00491-0"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2017.12.028"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2014.12.033"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp064742b"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.xcrp.2022.100829"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-019-1603-7"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.6b01340"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202514467","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/adma.202514467","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202514467","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,4,30]],"date-time":"2026-04-30T06:38:52Z","timestamp":1777531132000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202514467"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,11,5]]},"references-count":64,"journal-issue":{"issue":"6","published-print":{"date-parts":[[2026,1]]}},"alternative-id":["10.1002\/adma.202514467"],"URL":"https:\/\/doi.org\/10.1002\/adma.202514467","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,11,5]]},"assertion":[{"value":"2025-07-27","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-11-05","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e14467"}}