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These states exist within a narrow parameter window, making them difficult to stabilize. Here, it is shown for the selective oxidation of 2\u2010propanol to acetone over Co\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    spinels that the addition of water extends the stability regime of the relevant frustrated phase transition. This conclusion is based on results obtained from multi\u2010modal experiments, including\n                    <jats:italic>operando<\/jats:italic>\n                    scanning electron microscopy (OSEM), near ambient pressure X\u2010ray photoelectron spectroscopy (NAP\u2010XPS), transmission electron microscopy (TEM), and computer vision analysis. It is found that the most selective state for acetone formation coincides with a dynamic spinel structure that fluctuates through reversible redox processes. At elevated temperatures, this metastable state undergoes a complete phase transition into the rock\u2010salt CoO phase characterized by low acetone selectivity. This process is found to be mediated by the generation of mobile vacancies. The addition of water vapor mitigates vacancy mobility and stabilizes the selective, but thermodynamically frustrated, state. As such, the study conceptualizes a strategy to extend the lifetime of a catalyst during reaction by the adequate addition of a co\u2010reactant.\n                  <\/jats:p>","DOI":"10.1002\/adma.202515292","type":"journal-article","created":{"date-parts":[[2025,11,24]],"date-time":"2025-11-24T14:22:34Z","timestamp":1763994154000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Stabilizing Frustrated Phase Transitions in Selective Oxidation Reactions"],"prefix":"10.1002","volume":"38","author":[{"ORCID":"https:\/\/orcid.org\/0009-0003-6265-0623","authenticated-orcid":false,"given":"Luis","family":"Sandoval\u2010Diaz","sequence":"first","affiliation":[{"name":"Fritz\u2010Haber\u2010Institute of the Max\u2010Planck\u2010Society  14195 Berlin Germany"},{"name":"Bavarian Center for Battery Technology (BayBatt) University of Bayreuth  95448 Bayreuth 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