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Electrocatalysis provides an effective strategy to convert waste PET plastics into high\u2010value\u2010added chemicals under mild conditions, which can achieve enhanced recycling efficiency. Especially, when coupled with cathode reduction reactions such as hydrogen evolution, carbon dioxide reduction, nitrate reduction, etc., valuable chemicals can be concurrently produced at both anode and cathode. The corresponding coupling systems and their applicable electrocatalysts in the recycling process of PET waste have yet to be comprehensively reviewed. This review first describes the mechanisms of electrocatalytic PET upcycling in detail, and summarizes the electrochemical reforming strategies by emphasizing various anode\u2010cathode reaction coupling pathways and related intermediates. 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