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However, the rapid insertion\/extraction of Zn\n                    <jats:sup>2+<\/jats:sup>\n                    at high current densities triggers irreversible structural degradation and slow ion diffusion kinetics, leading to poor cycling stability. Herein, highly conductive Se is doped into a carbon skeleton of V\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    , realizing the orbital interaction between V 3d and Se 4p orbitals. Density functional theory calculations verify that the strong d\u2010p orbital hybridization upshifts the d\u2010band center of V, optimizes the charge distribution, and reduces the Zn\n                    <jats:sup>2+<\/jats:sup>\n                    and H\n                    <jats:sup>+<\/jats:sup>\n                    adsorption energies. Furthermore, the robust V\u2500Se covalent network in the Se\u2010V\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    @C electrode significantly enhances the electrode's redox activity and conductivity, resulting in high specific capacity and ultra\u2010long cycle life. Therefore, the Se\u2010V\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    @C\u2010650 electrode exhibits a high capacity of 460.87 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.1 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . When the current density is 10 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , the capacity reaches 168.32 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 10\u00a0000 cycles, with a 73.8% capacity retention after 20\u00a0000 cycles, which exceeds the reported electrodes. This work presents new insights for constructing high\u2010performance AZIB cathodes by establishing the mechanism of action between d\u2010p orbital hybridization and electrochemical performance.\n                  <\/jats:p>","DOI":"10.1002\/adma.202516093","type":"journal-article","created":{"date-parts":[[2025,10,24]],"date-time":"2025-10-24T07:25:28Z","timestamp":1761290728000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":23,"title":["V\n                    <sub>2<\/sub>\n                    O\n                    <sub>3<\/sub>\n                    with Se\u2010Enhanced d\u2010p Orbital Hybridization Toward Highly Stable Aqueous Zinc Batteries under 10 A g\n                    <sup>\u22121<\/sup>"],"prefix":"10.1002","volume":"38","author":[{"given":"Runmei","family":"Luo","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Jiangsu University  Zhenjiang 212013 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