{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T17:20:50Z","timestamp":1791480050990,"version":"4.3.4"},"reference-count":67,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2025,11,17]],"date-time":"2025-11-17T00:00:00Z","timestamp":1763337600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,11,17]],"date-time":"2025-11-17T00:00:00Z","timestamp":1763337600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2022YFE0113800"],"award-info":[{"award-number":["2022YFE0113800"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22122505"],"award-info":[{"award-number":["22122505"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21905247"],"award-info":[{"award-number":["21905247"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22279115"],"award-info":[{"award-number":["22279115"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Promising and diverse strategies have emerged for creating isolated catalytic active sites, such as single\u2010atom catalysts and single\u2010atom alloys, aiming at achieving efficient and selective catalysis. However, the structural tunability of isolated active sites has largely been restricted to their chemical compositions, primarily due to the absence of a higher\u2010order structure associated with these isolated atoms. To address this, an additional degree of freedom is introduced by incorporating functional groups onto these active sites. Specifically, metal\u2010oxo single sites are implanted onto metal surfaces to achieve geometric and electronic synergy. As a demonstration of this concept, bismuth single sites are embedded onto a palladium surface, promoting\n                    <jats:italic>p\u2010d<\/jats:italic>\n                    orbital hybridization and facilitating the formation of terminal Bi\u2010oxo species. This cooperative interaction optimizes the adsorption strength of intermediates through both covalent electronic hybridization and geometric interactions. The Bi\u2010oxo\u2010embedded Pd hybrid nanostructure, created through consecutive etching and displacement deposition, enables the simultaneous optimization of key intermediates for the electrocatalytic oxygen reduction reaction. Remarkably, this hybrid nanostructure achieves specific and mass activities 11.03 and 8.45 times greater than those of commercial Pt\/C, respectively. Furthermore, it demonstrates high stability and achieves a power density of 280 mW cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    in direct methanol fuel cells.\n                  <\/jats:p>","DOI":"10.1002\/adma.202516171","type":"journal-article","created":{"date-parts":[[2025,11,18]],"date-time":"2025-11-18T07:25:26Z","timestamp":1763450726000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Implanting Metal\u2010Oxo Single Sites on Metal Surface: A Path to Geometric and Electronic Synergy in Electrocatalysis"],"prefix":"10.1002","volume":"38","author":[{"given":"Hui","family":"Jin","sequence":"first","affiliation":[{"name":"Center for Electron Microscopy Zhejiang Key Laboratory of Surface and Interface Science and Engineering for Catalysts China\u2010Saudi Arabia Joint Laboratory on Microscopic Structural Engineering of Advanced Materials State Key Laboratory of Green Chemical Synthesis and Conversion and College of Chemical Engineering Zhejiang University of Technology  Hangzhou 310014 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinshu","family":"Tian","sequence":"additional","affiliation":[{"name":"Center for Electron Microscopy Zhejiang Key Laboratory of Surface and Interface Science and Engineering for Catalysts China\u2010Saudi Arabia Joint Laboratory on Microscopic Structural Engineering of Advanced Materials State Key Laboratory of Green Chemical Synthesis and Conversion and College of Chemical Engineering Zhejiang University of Technology  Hangzhou 310014 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ni","family":"Ouyang","sequence":"additional","affiliation":[{"name":"Center for Electron Microscopy Zhejiang Key Laboratory of Surface and Interface Science and Engineering for Catalysts China\u2010Saudi Arabia Joint Laboratory on Microscopic Structural Engineering of Advanced Materials State Key Laboratory of Green Chemical Synthesis and Conversion and College of Chemical Engineering Zhejiang University of Technology  Hangzhou 310014 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhi","family":"Wang","sequence":"additional","affiliation":[{"name":"Center for Electron Microscopy Zhejiang Key Laboratory of Surface and Interface Science and Engineering for Catalysts China\u2010Saudi Arabia Joint Laboratory on Microscopic Structural Engineering of Advanced Materials State Key Laboratory of Green Chemical Synthesis and Conversion and College of Chemical Engineering Zhejiang University of Technology  Hangzhou 310014 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yucheng","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chongzhi","family":"Zhu","sequence":"additional","affiliation":[{"name":"Center for Electron Microscopy Zhejiang Key Laboratory of Surface and Interface Science and Engineering for Catalysts China\u2010Saudi Arabia Joint Laboratory on Microscopic Structural Engineering of Advanced Materials State Key Laboratory of Green Chemical Synthesis and Conversion and College of Chemical Engineering Zhejiang University of Technology  Hangzhou 310014 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tianchun","family":"Cheng","sequence":"additional","affiliation":[{"name":"Center for Electron Microscopy Zhejiang Key Laboratory of Surface and Interface Science and Engineering for Catalysts China\u2010Saudi Arabia Joint Laboratory on Microscopic Structural Engineering of Advanced Materials State Key Laboratory of Green Chemical Synthesis and Conversion and College of Chemical Engineering Zhejiang University of Technology  Hangzhou 310014 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huimin","family":"Wen","sequence":"additional","affiliation":[{"name":"Center for Electron Microscopy Zhejiang Key Laboratory of Surface and Interface Science and Engineering for Catalysts China\u2010Saudi Arabia Joint Laboratory on Microscopic Structural Engineering of Advanced Materials State Key Laboratory of Green Chemical Synthesis and Conversion and College of Chemical Engineering Zhejiang University of Technology  Hangzhou 310014 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaonian","family":"Li","sequence":"additional","affiliation":[{"name":"Center for Electron Microscopy Zhejiang Key Laboratory of Surface and Interface Science and Engineering for Catalysts China\u2010Saudi Arabia Joint Laboratory on Microscopic Structural Engineering of Advanced Materials State Key Laboratory of Green Chemical Synthesis and Conversion and College of Chemical Engineering Zhejiang University of Technology  Hangzhou 310014 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiaoli","family":"Chen","sequence":"additional","affiliation":[{"name":"Center for Electron Microscopy Zhejiang Key Laboratory of Surface and Interface Science and Engineering for Catalysts China\u2010Saudi Arabia Joint Laboratory on Microscopic Structural Engineering of Advanced Materials State Key Laboratory of Green Chemical Synthesis and Conversion and College of Chemical Engineering Zhejiang University of Technology  Hangzhou 310014 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8150-7350","authenticated-orcid":false,"given":"Yihan","family":"Zhu","sequence":"additional","affiliation":[{"name":"Center for Electron Microscopy Zhejiang Key Laboratory of Surface and Interface Science and Engineering for Catalysts China\u2010Saudi Arabia Joint Laboratory on Microscopic Structural Engineering of Advanced Materials State Key Laboratory of Green Chemical Synthesis and Conversion and College of Chemical Engineering Zhejiang University of Technology  Hangzhou 310014 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,11,17]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c16098"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202417777"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2025.01.021"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.160400"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.3c00418"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120918"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-023-01424-6"},{"key":"e_1_2_9_8_1","first-page":"1","volume":"33","author":"Luo S.","year":"2021","journal-title":"Adv. Mater."},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c05946"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2023.05.001"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202500848"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c17444"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.1c01493"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.26599\/NRE.2023.9120082"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-023-01196-1"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-34619-5"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c03345"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-023-01263-2"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202404408"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202300550"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202309231"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-45990-w"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-025-01323-8"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202501531"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c01306"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-58679-5"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c03499"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202416126"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b07238"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c00656"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c03576"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/s42004-019-0196-2"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202302485"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202413673"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-023-06529-z"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c07459"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202510965"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202308349"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-024-00722-2"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c05674"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c04982"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-57643-7"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c00618"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202414989"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c02016"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c05446"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.2c05220"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202215021"},{"key":"e_1_2_9_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202313179"},{"key":"e_1_2_9_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202103383"},{"key":"e_1_2_9_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2024.109966"},{"key":"e_1_2_9_52_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-022-4299-1"},{"key":"e_1_2_9_53_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-022-01112-5"},{"key":"e_1_2_9_54_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aba9731"},{"key":"e_1_2_9_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.gee.2022.01.011"},{"key":"e_1_2_9_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202302561"},{"key":"e_1_2_9_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202202856"},{"key":"e_1_2_9_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.1c00147"},{"key":"e_1_2_9_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.9b05024"},{"key":"e_1_2_9_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c08116"},{"key":"e_1_2_9_61_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.122807"},{"key":"e_1_2_9_62_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.123006"},{"key":"e_1_2_9_63_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202202333"},{"key":"e_1_2_9_64_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.135539"},{"key":"e_1_2_9_65_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.142446"},{"key":"e_1_2_9_66_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202314565"},{"key":"e_1_2_9_67_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aah6133"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202516171","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/adma.202516171","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202516171","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,2,2]],"date-time":"2026-02-02T10:29:59Z","timestamp":1770028199000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202516171"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,11,17]]},"references-count":67,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2026,2]]}},"alternative-id":["10.1002\/adma.202516171"],"URL":"https:\/\/doi.org\/10.1002\/adma.202516171","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,11,17]]},"assertion":[{"value":"2025-08-19","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-11-17","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e16171"}}