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In recent years, significant progress has been made in material design, catalytic mechanism analysis, and electrolyzer optimization. However, there remains a gap between \u201claboratory science\u201d and \u201cengineering practice\u201d in current research. Most reviews are primarily based on the \u201cmaterial\u2010structure\u2010performance\u201d model and have not yet established an integrated technical landscape combining multi\u2010physics, multi\u2010scale, and artificial intelligence (AI). This review centers on the industrialization goals of eCO\n                    <jats:sub>2<\/jats:sub>\n                    RR, establishing a multi\u2010scale research framework spanning from fundamental mechanisms to systems engineering. It covers four core areas: atomic\u2010level mechanism interpretation and characterization, interface microenvironment regulation, external field\u2010assisted optimization, and AI\u2010driven material design and reaction prediction. Through the closed\u2010loop integration of mechanism\u2010characterization\u2010optimization, this review emphasizes an overall synergistic strategy from materials to devices and from experiments to systems, aiming to establish a systematic research pathway for eCO\n                    <jats:sub>2<\/jats:sub>\n                    RR. This work not only provides a comprehensive research blueprint for the eCO\n                    <jats:sub>2<\/jats:sub>\n                    RR field but also offers methodological and strategic references for AI\u2010enabled catalytic material development, external field\u2010coupled performance enhancement, and the engineering of electrochemical carbon resource conversion.\n                  <\/jats:p>","DOI":"10.1002\/adma.202516978","type":"journal-article","created":{"date-parts":[[2026,3,20]],"date-time":"2026-03-20T07:07:40Z","timestamp":1773990460000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Science\u2010Towards\u2010Technology Breakthrough in CO\n                    <sub>2<\/sub>\n                    Electroreduction: Multiphysics, Multiscale, and Artificial Intelligence Insights"],"prefix":"10.1002","volume":"38","author":[{"given":"Ping","family":"Hong","sequence":"first","affiliation":[{"name":"School of Environmental &amp; Chemical Engineering Jiangsu University of Science and Technology  Zhenjiang Jiangsu P. 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