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Herein, a universal strategy is proposed to enhance the efficiency of diverse electrocatalytic hydrogenation reactions (such as cyanide (CN\n                    <jats:sup>\u2212<\/jats:sup>\n                    ), nitrate (NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    ), carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ), or oxygen (O\n                    <jats:sub>2<\/jats:sub>\n                    ) reductions) based on the supply\u2010demand balance of H\n                    <jats:sup>*<\/jats:sup>\n                    . Through passivating the terminal oxygen sites with unsaturated coordination in Co\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    with grafted sulfur (Co\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    \u2010S), the free energy for H\n                    <jats:sup>*<\/jats:sup>\n                    generation increases from 0.17 to 0.41\u00a0eV, efficiently regulating its production rate to restrain its excess formation. The supply\u2010demand balance of H\n                    <jats:sup>*<\/jats:sup>\n                    promotes its utilization and suppresses HER, immensely improving the deep hydrogenation of CN\n                    <jats:sup>\u2212<\/jats:sup>\n                    (Faraday efficiency (FE\n                    <jats:sc>ch<\/jats:sc>\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sc>\/nh<\/jats:sc>\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sc>\/ch<\/jats:sc>\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sc>nh<\/jats:sc>\n                    <jats:sub>2<\/jats:sub>\n                    ): 19.6% \u2192 45.3%), NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    (FE\n                    <jats:sc>nh<\/jats:sc>\n                    <jats:sub>3<\/jats:sub>\n                    : 83% \u2192 100%), CO\n                    <jats:sub>2<\/jats:sub>\n                    (FE\n                    <jats:sub>CO<\/jats:sub>\n                    : 25.1% \u2192 51.7%) and O\n                    <jats:sub>2<\/jats:sub>\n                    (transferred electrons: 2.6 \u2192 3.6). This electrocatalytic system also exhibits excellent practical application potential, such as the cyanide\u2010containing wastewater treatment. This work offers a new idea to enhance the utilization efficiency of cathodic active species for electrocatalytic reduction reactions and provides technical support for the design and synthesis of highly efficient and stable electrode materials.\n                  <\/jats:p>","DOI":"10.1002\/adma.202517022","type":"journal-article","created":{"date-parts":[[2025,11,6]],"date-time":"2025-11-06T13:10:42Z","timestamp":1762434642000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Atomic Hydrogen Mediated Efficient Electrocatalytic Hydrogenation Reactions"],"prefix":"10.1002","volume":"38","author":[{"given":"Lei","family":"Tian","sequence":"first","affiliation":[{"name":"National\u2010Local Joint Engineering Research Center of Heavy Metals Pollutants Control and Resource Utilization Nanchang Hangkong University  Nanchang 330063 P. R. 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