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While surface coatings are used to mitigate structural degradation at high voltages, conventional full coverage coatings often fail to withstand the cyclic mechanical stress, resulting in crack formation and performance decay. Here, a multifunctional CeO\n                    <jats:sub>2<\/jats:sub>\n                    nanoparticle (NP) pinning structure is designed as a surface coating on LCO (LCO@CeO\n                    <jats:sub>2<\/jats:sub>\n                    ) to enable stable operation at a high cut\u2010off voltage of 4.6\u00a0V (vs Li\/Li\n                    <jats:sup>+<\/jats:sup>\n                    ). This surface pinning architecture balances structural integrity with minimal inactive material usage. The CeO\n                    <jats:sub>2<\/jats:sub>\n                    NPs are strategically anchored to the LCO surface, creating a pinning structure that accommodates volume changes and suppresses fracture formation in the cathode. Moreover, the CeO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010mediated fast Li\n                    <jats:sup>+<\/jats:sup>\n                    transport pathways are established, improving high\u2010rate capability. The interspersed CeO\n                    <jats:sub>2<\/jats:sub>\n                    NPs also act as oxygen reservoirs, stabilizing reversible (O\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sup>3\u2212<\/jats:sup>\n                    species during high\u2010voltage oxygen anionic redox reactions. Consequently, the optimized LCO@CeO\n                    <jats:sub>2<\/jats:sub>\n                    cathode achieves a capacity retention of 85.3% after 500 cycles at 1C and a high\u2010rate capacity of 124.8\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 10C. This CeO\n                    <jats:sub>2<\/jats:sub>\n                    NP pinning structure offers a novel practical strategy for designing durable high\u2010voltage layered cathodes.\n                  <\/jats:p>","DOI":"10.1002\/adma.202517074","type":"journal-article","created":{"date-parts":[[2025,10,4]],"date-time":"2025-10-04T10:50:13Z","timestamp":1759575013000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Nano\u2010Particulate Surface Pinning of CeO\n                    <sub>2<\/sub>\n                    Enables Durable High\u2010Voltage Lithium\u2010Ion Batteries"],"prefix":"10.1002","volume":"38","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1799-6591","authenticated-orcid":false,"given":"Zezhou","family":"Lin","sequence":"first","affiliation":[{"name":"Department of Applied Physics The Hong Kong Polytechnic University  Hong Kong 999077 China"},{"name":"Research Institute for Smart Energy The 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