{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T07:03:48Z","timestamp":1792739028717,"version":"4.5.0"},"reference-count":42,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2025,12,16]],"date-time":"2025-12-16T00:00:00Z","timestamp":1765843200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2025,12,16]],"date-time":"2025-12-16T00:00:00Z","timestamp":1765843200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["DMR\u20102419539"],"award-info":[{"award-number":["DMR\u20102419539"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Crystal phase engineering of inorganic materials is one of the most important strategies for achieving new material properties and functionality. Gold is well known to adopt the face\u2010centered\u2010cubic (fcc) structure, and it remains challenging to create new phases, but recent research on nanogold has provided exciting opportunities by achieving 2H (note: H denotes hexagonal), 4H, and body\u2010centered\u2010tetragonal (bct) phases. In the current work, an unusual non\u2010compact phase in 40\u2010atom gold nanoclusters is reported, which is in contrast to the close\u2010packed isomer of fcc structure. The non\u2010compact isomer exhibits exclusive square planes in a layer\u2010by\u2010layer stacking, hence giving rise to a unique 0.5 \u00c5 channel, whereas the fcc isomer is composed of close\u2010packed planes with a closed structure (i.e., no 1D channel). The two Au\n                    <jats:sub>40<\/jats:sub>\n                    isomers lead to a nearly two orders of magnitude difference in electronic excited\u2010state lifetime. The attainment of the new non\u2010compact phase in nanogold presents potential opportunities in terahertz emission owing to the strong electron\u2010vibration coupling, ion channeling and ion selection, artificial photosynthesis, and biocatalysis.\n                  <\/jats:p>","DOI":"10.1002\/adma.202517188","type":"journal-article","created":{"date-parts":[[2025,12,16]],"date-time":"2025-12-16T10:10:53Z","timestamp":1765879853000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Phase Engineering of Nanogold: Non\u2010Close Packed Square Planes in A\u2032B\u2032 Stacking with a 0.5 \u00c5 Channel"],"prefix":"10.1002","volume":"38","author":[{"given":"Yitong","family":"Wang","sequence":"first","affiliation":[{"name":"Department of Chemistry Carnegie Mellon University  Pittsburgh PA 15213 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